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钙钛矿太阳能电池的稳定性:A 位阳离子和 X 位阴离子取代的前景展望。

Stability of Perovskite Solar Cells: A Prospective on the Substitution of the A Cation and X Anion.

机构信息

Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM), Jiangsu National Synergistic Innovation Center for Advanced Materials (SICAM), Nanjing Tech University (NanjingTech), 30 South Puzhu Road, Nanjing, 211816, P.R. China.

出版信息

Angew Chem Int Ed Engl. 2017 Jan 24;56(5):1190-1212. doi: 10.1002/anie.201603694. Epub 2016 Nov 28.

Abstract

In recent years, organometal trihalide perovskites have emerged as promising materials for low-cost, flexible, and highly efficient solar cells. Despite their processing advantages, before the technology can be commercialized the poor stability of the organic-inorganic hybrid perovskite materials with regard to humidity, heat, light, and oxygen has be to overcome. Herein, we distill the current state-of-the-art and highlight recent advances in improving the chemical stability of perovskite materials by substitution of the A-cation and X-anion. Our hope is to pave the way for the rational design of perovskite materials to realize perovskite solar cells with unprecedented improvement in stability.

摘要

近年来,有机金属卤化物钙钛矿作为低成本、柔性和高效太阳能电池的有前途的材料而出现。尽管它们具有加工优势,但在该技术实现商业化之前,必须克服有机-无机杂化钙钛矿材料对湿度、热、光和氧的较差稳定性。在此,我们总结了当前的最新进展,并强调了通过取代 A 阳离子和 X 阴离子来提高钙钛矿材料化学稳定性的最新进展。我们希望为钙钛矿材料的合理设计铺平道路,从而实现稳定性得到前所未有的提高的钙钛矿太阳能电池。

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