基于杂原子取代的萘二酰亚胺-苯并噻二唑共聚物的高性能、空气稳定的场效应晶体管，具有高达 8.5 cm V s 的超高电子迁移率。
High-Performance, Air-Stable Field-Effect Transistors Based on Heteroatom-Substituted Naphthalenediimide-Benzothiadiazole Copolymers Exhibiting Ultrahigh Electron Mobility up to 8.5 cm V s.
机构信息
Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education and Key Laboratory of Advanced Functional Polymeric Materials of College of Hunan Province, College of Chemistry, Xiangtan University, Xiangtan, 411105, P. R. China.
Beijing National Laboratory for Molecular Sciences, Chinese Academy of Sciences, Beijing, 100190, P. R. China.
出版信息
Adv Mater. 2017 Jan;29(4). doi: 10.1002/adma.201602410. Epub 2016 Dec 6.
Rational heteroatom engineering is applied to develop high-performance electron-transporting naphthalenediimide copolymers. Top-gate field-effect transistors fabricated from selenophene-containing polymers achieve an ultrahigh electron mobility of 8.5 cm V s and excellent air-stability. The results demonstrate that the incorporation of selenophene heterocycles into the polymers can improve the film-forming ability, intermolecular interaction, and carrier transport significantly.
理性的杂原子工程被应用于开发高性能电子传输萘二酰亚胺共聚物。由噻吩单元包含的聚合物制备的顶栅场效应晶体管实现了超高的电子迁移率 8.5 cm V s 和优异的空气稳定性。结果表明，噻吩杂环的引入可以显著改善聚合物的成膜能力、分子间相互作用和载流子输运。
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