• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

亚乙烯基与苯并[][1,2,5]噻二唑：π-间隔单元对用于n沟道有机场效应晶体管的含苯并二呋喃二酮的双(2-氧代吲哚啉-3-亚基)聚合物性能的影响

Vinylene and benzo[][1,2,5]thiadiazole: effect of the π-spacer unit on the properties of bis(2-oxoindolin-3-ylidene)-benzodifuran-dione containing polymers for n-channel organic field-effect transistors.

作者信息

Do Thu Trang, Patil Basanagouda B, Singh Samarendra P, Yambem Soniya D, Feron Krishna, Ostrikov Kostya Ken, Bell John M, Sonar Prashant

机构信息

School of Chemistry, Physics and Mechanical Engineering, Queensland University of Technology (QUT) 2 George Street Brisbane QLD-4001 Australia

Department of Physics, School of Natural Sciences, Shiv Nadar University (SNU) Gautam Buddha Nagar Uttar Pradesh India-201307.

出版信息

RSC Adv. 2018 Nov 20;8(68):38919-38928. doi: 10.1039/c8ra08890j. eCollection 2018 Nov 16.

DOI:10.1039/c8ra08890j
PMID:35558294
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9090616/
Abstract

Two polymers based on (3,7)-3,7-bis(2-oxoindolin-3-ylidene)benzo[1,2-:4,5-']difuran-2,6(3,7)-dione (BIBDF) coupled with ()-2-(2-(thiophen-2-yl)vinyl)thiophene (TVT) or dithienylbenzothiadiazole (TBT), namely PBIBDF-TVT and PBIBDF-TBT were synthesized the Stille coupling reaction. The effect of benzothiadiazole or vinylene-π spacer of the copolymers on optical properties, energy levels, electronic device performance and microstructure were studied. It was found that PBIBDF-TBT based OFET devices, annealed at 180 °C, showed better performance with the highest electron mobility of 2.9 × 10 cm V s whereas PBIBDF-TVT polymer exhibited 5.0 × 10 cm V s. The two orders of magnitude higher electron mobility of PBIBDF-TBT over PBIBDT-TVT is a clear indicator of the better charge transport ability of this polymer semiconductor arising from its higher crystallinity and better donor-acceptor interaction.

摘要

基于(3,7)-3,7-双(2-氧代吲哚啉-3-亚基)苯并[1,2-:4,5-']二呋喃-2,6(3,7)-二酮(BIBDF)与()-2-(2-(噻吩-2-基)乙烯基)噻吩(TVT)或二噻吩基苯并噻二唑(TBT)偶联的两种聚合物，即PBIBDF-TVT和PBIBDF-TBT，通过Stille偶联反应合成。研究了共聚物中苯并噻二唑或亚乙烯基-π间隔基对光学性质、能级、电子器件性能和微观结构的影响。结果发现，在180℃退火的基于PBIBDF-TBT的有机场效应晶体管器件表现出更好的性能，最高电子迁移率为2.9×10 cm V s，而PBIBDF-TVT聚合物的电子迁移率为5.0×10 cm V s。PBIBDF-TBT的电子迁移率比PBIBDT-TVT高两个数量级，这清楚地表明该聚合物半导体由于其更高的结晶度和更好的供体-受体相互作用而具有更好的电荷传输能力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a52a/9090616/55a95ac38164/c8ra08890j-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a52a/9090616/99c715ff8379/c8ra08890j-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a52a/9090616/ba8af57cc749/c8ra08890j-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a52a/9090616/389c5b85e95c/c8ra08890j-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a52a/9090616/8fbb5008590f/c8ra08890j-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a52a/9090616/81b1a9a9c15d/c8ra08890j-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a52a/9090616/ac157d86fc6e/c8ra08890j-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a52a/9090616/9e23c5f92828/c8ra08890j-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a52a/9090616/03d5ee72f01d/c8ra08890j-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a52a/9090616/55a95ac38164/c8ra08890j-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a52a/9090616/99c715ff8379/c8ra08890j-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a52a/9090616/ba8af57cc749/c8ra08890j-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a52a/9090616/389c5b85e95c/c8ra08890j-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a52a/9090616/8fbb5008590f/c8ra08890j-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a52a/9090616/81b1a9a9c15d/c8ra08890j-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a52a/9090616/ac157d86fc6e/c8ra08890j-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a52a/9090616/9e23c5f92828/c8ra08890j-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a52a/9090616/03d5ee72f01d/c8ra08890j-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a52a/9090616/55a95ac38164/c8ra08890j-f7.jpg

相似文献

1
Vinylene and benzo[][1,2,5]thiadiazole: effect of the π-spacer unit on the properties of bis(2-oxoindolin-3-ylidene)-benzodifuran-dione containing polymers for n-channel organic field-effect transistors.亚乙烯基与苯并[][1,2,5]噻二唑：π-间隔单元对用于n沟道有机场效应晶体管的含苯并二呋喃二酮的双(2-氧代吲哚啉-3-亚基)聚合物性能的影响
RSC Adv. 2018 Nov 20;8(68):38919-38928. doi: 10.1039/c8ra08890j. eCollection 2018 Nov 16.
2
Novel stable (3E,7E)-3,7-bis(2-oxoindolin-3-ylidene)benzo[1,2-b:4,5-b']difuran-2,6(3H,7H)-dione based donor-acceptor polymer semiconductors for n-type organic thin film transistors.基于（3E，7E）-3，7-双（2-氧代吲哚啉-3-亚基）苯并[1,2-b：4,5-b']二呋喃-2,6（3H，7H）-二酮的新型稳定给体-受体聚合物半导体，用于 n 型有机薄膜晶体管。
Chem Commun (Camb). 2013 May 8;49(36):3790-2. doi: 10.1039/c3cc40531a. Epub 2013 Apr 2.
3
A bis(2-oxoindolin-3-ylidene)-benzodifuran-dione containing copolymer for high-mobility ambipolar transistors.用于高迁移率双极性晶体管的含双（2-氧代吲哚啉-3-亚基）-苯并二呋喃二酮共聚物。
Chem Commun (Camb). 2014 Mar 25;50(24):3180-3. doi: 10.1039/c3cc48695h. Epub 2014 Feb 12.
4
(3E,8E)-3,8-Bis(2-oxoindolin-3-ylidene)naphtho-[1,2-b:5,6-b']difuran-2,7(3H,8H)-dione (INDF) based polymers for organic thin-film transistors with highly balanced ambipolar charge transport characteristics.用于具有高度平衡双极性电荷传输特性的有机薄膜晶体管的基于(3E,8E)-3,8-双(2-氧代吲哚啉-3-亚基)萘并-[1,2-b:5,6-b']二呋喃-2,7(3H,8H)-二酮(INDF)的聚合物
Chem Commun (Camb). 2015 Sep 11;51(70):13515-8. doi: 10.1039/c5cc03917g.
5
(3E,7E)-3,7-Bis(2-oxoindolin-3-ylidene)-5,7-dihydropyrrolo[2,3-f]indole-2,6(1H,3H)-dione based polymers for ambipolar organic thin film transistors.用于双极性有机薄膜晶体管的基于(3E,7E)-3,7-双(2-氧代吲哚啉-3-亚基)-5,7-二氢吡咯并[2,3-f]吲哚-2,6(1H,3H)-二酮的聚合物
Chem Commun (Camb). 2015 May 11;51(38):8093-6. doi: 10.1039/c5cc01021g. Epub 2015 Apr 14.
6
Effect of Backbone Sequence of a Naphthalene Diimide-Based Copolymer on Performance in n-Type Organic Thin-Film Transistors.基于萘二酰亚胺的共聚物的骨架序列对 n 型有机薄膜晶体管性能的影响。
ACS Appl Mater Interfaces. 2019 Sep 25;11(38):35185-35192. doi: 10.1021/acsami.9b09607. Epub 2019 Sep 10.
7
Well-Balanced Ambipolar Conjugated Polymers Featuring Mild Glass Transition Temperatures Toward High-Performance Flexible Field-Effect Transistors.具有温和玻璃化转变温度的平衡双极性共轭聚合物，实现高性能柔性场效应晶体管。
Adv Mater. 2018 Mar;30(9). doi: 10.1002/adma.201705286. Epub 2018 Jan 12.
8
Synthesis and Photophysical Studies of Thiadiazole[3,4-c]pyridine Copolymer Based Organic Field-Effect Transistors.基于噻二唑并[3,4-c]吡啶共聚物的有机场效应晶体管的合成与光物理研究
J Fluoresc. 2016 May;26(3):1045-52. doi: 10.1007/s10895-016-1792-5. Epub 2016 Apr 7.
9
Centrosymmetric Thiophenemethyleneoxindole-Based Donor-Acceptor Copolymers for Organic Field-Effect Transistors.基于中心对称噻吩亚甲基氧吲哚的给体-受体共聚物用于有机场效应晶体管。
Macromol Rapid Commun. 2018 Jun;39(11):e1800073. doi: 10.1002/marc.201800073. Epub 2018 May 3.
10
Thieno[3,4-b]thiophene-Based Novel Small-Molecule Optoelectronic Materials.基于噻吩并[3,4-b]噻吩的新型小分子光电材料。
Acc Chem Res. 2017 Jun 20;50(6):1342-1350. doi: 10.1021/acs.accounts.7b00050. Epub 2017 Apr 4.

本文引用的文献

1
Integrated circuits based on conjugated polymer monolayer.基于共轭聚合物单层的集成电路。
Nat Commun. 2018 Jan 31;9(1):451. doi: 10.1038/s41467-017-02805-5.
2
Bis-Diketopyrrolopyrrole Moiety as a Promising Building Block to Enable Balanced Ambipolar Polymers for Flexible Transistors.双二酮吡咯并吡咯部分作为一个有前途的构建块，实现了用于柔性晶体管的平衡双极性聚合物。
Adv Mater. 2017 Jun;29(22). doi: 10.1002/adma.201606162. Epub 2017 Mar 29.
3
Mechanical Properties of Organic Semiconductors for Stretchable, Highly Flexible, and Mechanically Robust Electronics.
用于可拉伸、高柔性和机械坚固电子设备的有机半导体的机械性能。
Chem Rev. 2017 May 10;117(9):6467-6499. doi: 10.1021/acs.chemrev.7b00003. Epub 2017 Mar 25.
4
High-Performance, Air-Stable Field-Effect Transistors Based on Heteroatom-Substituted Naphthalenediimide-Benzothiadiazole Copolymers Exhibiting Ultrahigh Electron Mobility up to 8.5 cm V s.基于杂原子取代的萘二酰亚胺-苯并噻二唑共聚物的高性能、空气稳定的场效应晶体管，具有高达 8.5 cm V s 的超高电子迁移率。
Adv Mater. 2017 Jan;29(4). doi: 10.1002/adma.201602410. Epub 2016 Dec 6.
5
Strong Electron-Deficient Polymers Lead to High Electron Mobility in Air and Their Morphology-Dependent Transport Behaviors.强缺电子聚合物导致其在空气中具有高电子迁移率及其形态依赖性输运行为。
Adv Mater. 2016 Sep;28(33):7213-9. doi: 10.1002/adma.201600541. Epub 2016 Jun 7.
6
A Highly Sensitive Diketopyrrolopyrrole-Based Ambipolar Transistor for Selective Detection and Discrimination of Xylene Isomers.基于二酮吡咯并吡咯的高灵敏度双极性晶体管，用于对二甲苯异构体的选择性检测和区分。
Adv Mater. 2016 Jun;28(21):4012-8. doi: 10.1002/adma.201505641. Epub 2016 Mar 21.
7
Side-Chain-Induced Rigid Backbone Organization of Polymer Semiconductors through Semifluoroalkyl Side Chains.通过半氟烷基侧链诱导聚合物半导体的侧链刚性骨架组织。
J Am Chem Soc. 2016 Mar 23;138(11):3679-86. doi: 10.1021/jacs.5b10445. Epub 2016 Jan 12.
8
Fine-Tuning of Crystal Packing and Charge Transport Properties of BDOPV Derivatives through Fluorine Substitution.通过氟取代对 BDOPV 衍生物的晶体堆积和电荷输运性质进行微调。
J Am Chem Soc. 2015 Dec 23;137(50):15947-56. doi: 10.1021/jacs.5b11114. Epub 2015 Dec 9.
9
Asymmetric Diketopyrrolopyrrole Conjugated Polymers for Field-Effect Transistors and Polymer Solar Cells Processed from a Nonchlorinated Solvent.非氯化溶剂加工的用于场效应晶体管和聚合物太阳能电池的不对称二酮吡咯并吡咯共轭聚合物。
Adv Mater. 2016 Feb 3;28(5):943-50. doi: 10.1002/adma.201504272. Epub 2015 Nov 30.
10
A Cofacially Stacked Electron-Deficient Small Molecule with a High Electron Mobility of over 10 cm(2) V(-1) s(-1) in Air.在空气中具有超过 10 cm(2) V(-1) s(-1) 的高电子迁移率的共面堆叠电子缺小分子。
Adv Mater. 2015 Dec 22;27(48):8051-5. doi: 10.1002/adma.201503803. Epub 2015 Oct 26.