School of Chemistry and Environmental Engineering, Jiangsu University of Technology , Changzhou 213001, P. R. China.
School of Petrochemical Engineering, Jiangsu Key Laboratory of Advanced Catalytic Materials & Technology, Changzhou University , Changzhou 213164, P. R. China.
J Org Chem. 2016 Dec 2;81(23):12065-12069. doi: 10.1021/acs.joc.6b02451. Epub 2016 Nov 17.
The oxidative difunctionalization of aryl alkynoates with alphatic aldehydes as a cheap and abundant alkyl radical source was developed, providing a variety of trisubstituted alkenes in moderate to good yields. In this reaction, radical decarbonylative alkylation of C-C triple bond, 1,4-aryl migration, and decarboxylation were involved under metal-free conditions.
开发了一种以脂肪醛作为廉价丰富的烷基自由基源，对芳基炔酸酯进行氧化双官能化的方法，以中等到良好的收率得到了多种三取代烯烃。在该反应中，在无金属条件下，涉及 C-C 三键的自由基脱羰烷基化、1,4-芳基迁移和脱羧反应。
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