Yu Jin-Tao, Chen Rongzhen, Zhu Jiawei, Cheng Jiang
School of Petrochemical Engineering, Jiangsu Key Laboratory of Advanced Catalytic Materials & Technology, Changzhou University, Changzhou 213164, P. R. China.
Org Biomol Chem. 2017 Jul 5;15(26):5476-5479. doi: 10.1039/c7ob01260h.
A metal-free decarbonylative arylalkylation of N-(arylsulfonyl)acrylamides using aliphatic aldehydes as the alkyl radical source was developed, providing a series of α-aryl-β-alkylamides in moderate to good yields. In this reaction, concomitant alkylation, aryl migration and desulfonylation were involved.
开发了一种以脂肪醛为烷基自由基源的N-（芳基磺酰基）丙烯酰胺的无金属脱羰芳基烷基化反应，以中等至良好的产率提供了一系列α-芳基-β-烷基酰胺。在该反应中，涉及伴随的烷基化、芳基迁移和脱磺酰化反应。
Zotero 插件