Sharpe Helen R, Geer Ana M, Williams Huw E L, Blundell Toby J, Lewis William, Blake Alexander J, Kays Deborah L
School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD, UK.
Centre for Biomolecular Sciences, University of Nottingham, University Park, Nottingham, NG7 2RD, UK.
Chem Commun (Camb). 2017 Jan 10;53(5):937-940. doi: 10.1039/c6cc07243g.
Two- and three-coordinate m-terphenyl complexes of manganese and iron are efficient catalysts for the selective cyclotrimerisation of primary aliphatic isocyanates affording isocyanurates in short reaction times and under mild conditions.
锰和铁的二配位及三配位间三联苯配合物是高效催化剂，可在短反应时间和温和条件下，将伯脂肪族异氰酸酯选择性环三聚生成异氰脲酸酯。
