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一种新开发的低杨氏模量Ti-15Zr-5Cr-2Al生物医学合金的微观结构与力学性能

Microstructure and mechanical properties of a newly developed low Young's modulus Ti-15Zr-5Cr-2Al biomedical alloy.

作者信息

Wang Pan, Wu Lihong, Feng Yan, Bai Jiaming, Zhang Baicheng, Song Jie, Guan Shaokang

机构信息

School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450002, PR China; Singapore Institute of Manufacturing Technology, 71 Nanyang Drive, Singapore 638075, Singapore.

School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450002, PR China.

出版信息

Mater Sci Eng C Mater Biol Appl. 2017 Mar 1;72:536-542. doi: 10.1016/j.msec.2016.11.101. Epub 2016 Nov 26.

Abstract

The Ti-15Zr-5Cr-2Al alloy has been developed and various heat treatments have been investigated to develop new biomedical materials. It is found that the heat treatment conditions strongly affect the phase constitutions and mechanical properties. The as-cast specimen is comprised of β phase and a small fraction of α phase, which is attributed to the suppression of ω phase caused by adding Al. A high yield strength of 1148±36MPa and moderate Young's modulus of 96±3GPa are obtained in the as-cast specimen. Besides the β phase and α phase, ω phase is also detected in the air cooled and liquid nitrogen quenched specimens, which increases the Young's modulus and lowers the ductility. In contrast, only β phase is detected after ice water quenching. The ice water quenched specimen exhibits a good combination of mechanical properties with a high microhardness of 302±10HV, a large plastic strain of 23±2%, a low Young's modulus of 58±4GPa, a moderate yield strength of 625±32MPa and a high compressive strength of 1880±59MPa. Moreover, the elastic energies of the ice water quenched specimen (3.22MJ/m) and as-cast specimen (6.86MJ/m) are higher than that of c.p. Ti (1.25MJ/m). These results demonstrate that as-cast and ice water quenched Ti-15Zr-5Cr-2Al alloys with a superior combination of mechanical properties are potential materials for biomedical applications.

摘要

已研发出Ti-15Zr-5Cr-2Al合金,并对各种热处理工艺进行了研究,以开发新型生物医学材料。研究发现,热处理条件对相组成和力学性能有强烈影响。铸态试样由β相和少量α相组成,这归因于添加Al对ω相的抑制作用。铸态试样的屈服强度高达1148±36MPa,杨氏模量适中,为96±3GPa。除β相和α相外,在空冷和液氮淬火试样中还检测到ω相,这会提高杨氏模量并降低延展性。相比之下,冰水淬火后仅检测到β相。冰水淬火试样展现出良好的力学性能组合,显微硬度高达302±10HV,塑性应变大,为23±2%,杨氏模量低,为58±4GPa,屈服强度适中,为625±32MPa,抗压强度高,为1880±59MPa。此外,冰水淬火试样(3.22MJ/m)和铸态试样(6.86MJ/m)的弹性能高于纯钛(1.25MJ/m)。这些结果表明,具有优异力学性能组合的铸态和冰水淬火Ti-15Zr-5Cr-2Al合金是生物医学应用的潜在材料。

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