Hydrotox GmbH, Freiburg, Germany.
Hydrotox GmbH, Freiburg, Germany.
Chemosphere. 2017 Mar;171:580-587. doi: 10.1016/j.chemosphere.2016.12.115. Epub 2016 Dec 23.
The European Construction Products Regulation allows Member States to adopt rules for evaluating the environmental impact of their buildings. The aim of the project was to develop recommendations for a test battery for the ecotoxicological assessment of the environmental impact of construction products for outdoor use and contribute to the European harmonization of test methods. From a shortlist of 39 products 20 products were included in the ecotoxicological testing program. Monolithic and plate-like construction products were eluted in the Dynamic Surface Leaching test (DSLT) in accordance with CEN/TS 16637-2, granular products were eluted in a one stage batch test in accordance with DIN EN 12457-1. The eluates were examined in four aquatic toxicity tests (algae, daphnia, luminescent bacteria, fish eggs), a genotoxicity test (umu test) and in the respirometer test (OECD 301 F). Here, low to very high ecotoxicity was observed (up to a dilution factor of 1536). Six out of 8 eluates, whose TOC exceeded 10 mg L showed a good biodegradability above 75%. The intra-laboratory repeatability of the Lowest Ineffective Dilution (LID) usually was within ±1 dilution steps (ecotoxicity tests) and ±2 dilution steps (leaching and ecotoxicity tests). This is acceptable, when considering that the overall variability of sample preparation, leaching test, and bioassays add up. The conclusions lead to practical recommendations for a suitable combination of leaching and ecotoxicity tests.
欧洲建筑产品法规允许成员国制定评估建筑物环境影响的规则。该项目的目的是为户外使用的建筑产品的生态毒理学评估开发测试电池的建议,并为欧洲测试方法的协调做出贡献。从 39 种产品的短名单中,有 20 种产品被纳入生态毒理学测试计划。整体式和板状建筑产品根据 CEN/TS 16637-2 在动态表面浸出测试(DSLT)中浸出,颗粒状产品根据 DIN EN 12457-1 在一个阶段批量测试中浸出。浸出液在四个水生毒性测试(藻类、水蚤、发光细菌、鱼卵)、遗传毒性测试(umu 测试)和呼吸计测试(OECD 301 F)中进行了检查。在这里,观察到低至非常高的生态毒性(高达稀释因子 1536)。六份总有机碳(TOC)超过 10mg/L 的浸出液显示出良好的生物降解性,超过 75%。低无效稀释度(LID)的实验室内部重复性通常在±1 稀释度步骤(毒性测试)和±2 稀释度步骤(浸出和毒性测试)内。当考虑到样品制备、浸出试验和生物测定的整体变异性时,这是可以接受的。这些结论为浸出和生态毒性测试的合适组合提供了实用建议。