一种超稳定的锆膦酸盐骨架作为用于高活性CO化学转化的双功能催化剂。
An ultrastable zirconium-phosphonate framework as bifunctional catalyst for highly active CO chemical transformation.
作者信息
Gao Chao-Ying, Ai Jing, Tian Hong-Rui, Wu Dai, Sun Zhong-Ming
机构信息
College of Chemistry and Chemical Engineering, Inner Mongolia University for the Nationalities, Tongliao 02800, P. R. China and State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, China.
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, China.
出版信息
Chem Commun (Camb). 2017 Jan 19;53(7):1293-1296. doi: 10.1039/c6cc08773f.
A zirconium-phosphonate network, as a bifunctional catalyst for carbon dioxide (CO)/epoxide coupling reaction, exhibits very high activity that is superior to most documented metal-organic framework (MOF)-based catalysts. Furthermore, it possesses extraordinary tolerance to extremely harsh conditions, such as aqua regia. This paper describes the use of metal phosphonate as a new MOF applied to CO transformation.
一种膦酸锆网络作为二氧化碳（CO）/环氧化物偶联反应的双功能催化剂，表现出非常高的活性，优于大多数已报道的基于金属有机框架（MOF）的催化剂。此外，它对王水等极端苛刻条件具有非凡的耐受性。本文描述了膦酸金属作为一种应用于CO转化的新型MOF的用途。
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