亲核手性膦：用于不对称环化反应的强大且通用的催化剂。
Nucleophilic Chiral Phosphines: Powerful and Versatile Catalysts for Asymmetric Annulations.
作者信息
Xiao Yumei, Guo Hongchao, Kwon Ohyun
机构信息
Department of Applied Chemistry, China Agricultural University, Beijing 100193, P. R. China.
Department of Chemistry and Biochemistry, The University of California, Los Angeles, Los Angeles, CA 90095, USA.
出版信息
Aldrichimica Acta. 2016;49(1):3-13.
Abstract
Recent advances in chiral-phosphine-catalyzed asymmetric annulation reactions; including annulations of allenes, alkynes, Morita-Baylis-Hillman (MBH) carbonates, and ketenes; and their applications in the synthesis of bioactive molecules and natural products are reviewed.
摘要
综述了手性膦催化的不对称环化反应的最新进展，包括丙二烯、炔烃、Morita-Baylis-Hillman（MBH）碳酸酯和烯酮的环化反应，以及它们在生物活性分子和天然产物合成中的应用。
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