碘介导的甲基酮C-H官能化：通过吡啶叶立德与炔酮之间的1,3-偶极环加成反应一锅法合成官能化中氮茚。
Iodine-mediated C-H functionalization of methyl ketones: a one-pot synthesis of functionalized indolizines via the 1,3-dipolar cycloaddition reaction between pyridinium ylides and ynones.
作者信息
Yavari Issa, Sheykhahmadi Jamil, Naeimabadi Maryam, Halvagar Mohammad Reza
机构信息
Department of Chemistry, Tarbiat Modares University, PO Box 14115-175, Tehran, Iran.
Department of Inorganic Chemistry, Chemistry and Chemical Engineering Research Center of Iran, PO Box 14335-186, Tehran, Iran.
出版信息
Mol Divers. 2017 Feb;21(1):1-8. doi: 10.1007/s11030-016-9720-9. Epub 2017 Jan 11.
An efficient transition-metal-free approach toward C-H bond activation by using molecular [Formula: see text]-mediated [Formula: see text] C-H bond functionalization for the synthesis of indolizine derivatives via 1,3-dipolar cycloaddition reaction of nitrogen ylides with ynones is described.
描述了一种高效的无过渡金属方法，通过使用分子[化学式：见原文]介导的[化学式：见原文]C-H键官能化，实现C-H键活化，用于经由氮叶立德与炔酮的1,3-偶极环加成反应合成中氮茚衍生物。
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