（6,20）-3,24-二氟-13,14,28,29-四氢-5,22-四苯并[,,,][1,4,12,15]四氧杂环二十二碳-5,22-二酮的晶体结构
Crystal structure of (6,20)-3,24-di-fluoro-13,14,28,29-tetra-hydro-5,22-tetra-benzo[,,,][1,4,12,15]tetra-oxa-cyclo-docosine-5,22-dione.
作者信息
Mohamed Shaaban K, Akkurt Mehmet, Hawaiz Farouq E, Ayoob Mzgin M, Hosten Eric
机构信息
Chemistry and Environmental Division, Manchester Metropolitan University, Manchester, M1 5GD, England, and, Chemistry Department, Faculty of Science, Minia University, 61519 El-Minia, Egypt.
Department of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, Turkey.
出版信息
Acta Crystallogr E Crystallogr Commun. 2017 Jan 1;73(Pt 1):13-16. doi: 10.1107/S2056989016018934.
The conformation of the title compound, CHFO, is cone-shaped, partially determined by intra-molecular C-H⋯O short contacts. The benzene rings at the top of the cone are inclined to one another by 73.10 (7)°, while the benzene rings at the bottom of the cone are inclined to one another by 35.49 (8)°. In the crystal, mol-ecules are linked by C-H⋯O and C-H⋯F hydrogen bonds, forming a three-dimensional supra-molecular structure. There are also C-H⋯π contacts present within the framework structure.
标题化合物CHFO的构象为锥形，部分由分子内C-H⋯O短接触决定。锥顶的苯环相互倾斜73.10 (7)°，而锥底的苯环相互倾斜35.49 (8)°。在晶体中，分子通过C-H⋯O和C-H⋯F氢键相连，形成三维超分子结构。框架结构内还存在C-H⋯π接触。
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