从醇和 CO 合成碳酸盐。
Synthesis of Carbonates from Alcohols and CO.
机构信息
The Barcelona Institute of Science and Technology, Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007, Tarragona, Spain.
Catalan Institute of Research and Advanced Studies (ICREA), Pg. Lluis Companys 23, 08010, Barcelona, Spain.
出版信息
Top Curr Chem (Cham). 2017 Feb;375(1):15. doi: 10.1007/s41061-016-0101-8. Epub 2017 Jan 18.
Alcohols are ubiquitous compounds in nature that offer modular building blocks for synthetic chemistry. Here we discuss the most recent development of different classes of alcohols and their coupling chemistry with carbon dioxide as to afford linear and cyclic carbonates, the challenges associated with their formation, and the potential of this chemistry to revive a waste carbon feed stock.
醇类是自然界中无处不在的化合物，为合成化学提供了模块化的构建块。在这里，我们讨论了不同类型的醇类及其与二氧化碳的偶联化学，以提供线性和环状碳酸酯，讨论了它们形成所面临的挑战，以及这种化学在使废弃碳原料重新焕发生机方面的潜力。
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