烯烃与一氧化碳的氧化羧化反应：通往五元环状碳酸酯的环境友好途径

Oxidative carboxylation of olefins with CO: environmentally benign access to five-membered cyclic carbonates.

作者信息

Wang Liang, Que Sisi, Ding Ziwei, Vessally Esmail

机构信息

State Key Lab of Coal Mine Disaster Dynamics and Control, Chongqing University Chongqing 400044 China.

State Key Laboratory of Coal Resources in Western China, Xi'an University of Science and Technology Xi'an 710054 China.

出版信息

RSC Adv. 2020 Mar 3;10(15):9103-9115. doi: 10.1039/c9ra10755j. eCollection 2020 Feb 27.

The purpose of this focus review is to provide a comprehensive overview of the direct synthesis of five-membered cyclic carbonates oxidative carboxylation of the corresponding olefins and carbon dioxide with particular attention on the mechanistic features of the reactions. The review is divided into two main sections. The first section is a discussion of the single-step reactions, while the second consists of an overview of one-pot, two-step sequential reactions.