Arshadi Sattar, Banaei Alireza, Ebrahimiasl Saeideh, Monfared Aazam, Vessally Esmail
Department of Chemistry, Payame Noor University P. O. Box 19395-1697 Tehran Iran
Department of Chemistry, Ahar Branch, Islamic Azad University Ahar Iran.
RSC Adv. 2019 Jun 21;9(34):19465-19482. doi: 10.1039/c9ra00551j. eCollection 2019 Jun 19.
This review is an attempt to give an overview on the recent advances and developments in the synthesis of 2-oxazolidinone frameworks through carbon dioxide (CO) fixation reactions under solvent-free conditions. The cycloaddition of CO to aziridine derivatives is discussed first. This is followed by carboxylative cyclization of -propargylamines with CO and three-component coupling of epoxides, amines, and CO. Finally, cycloaddition of CO to propargylic alcohols and amines will be covered at the end of the review. The literature has been surveyed up until the end of 2018.
本综述旨在概述在无溶剂条件下通过二氧化碳（CO₂）固定反应合成2-恶唑烷酮骨架的最新进展和发展情况。首先讨论了CO₂与氮丙啶衍生物的环加成反应。接着是α-炔丙基胺与CO₂的羧基环化反应以及环氧化物、胺和CO₂的三组分偶联反应。最后，本综述末尾将涵盖CO₂与炔丙醇和胺的环加成反应。已对截至2018年底的文献进行了调研。
