Peng Youbin, Liu Juan, Qi Chaorong, Yuan Gaoqing, Li Jiawei, Jiang Huanfeng
School of Chemistry and Chemical Engineering, State Key Lab of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510640, P. R. China.
Key Lab of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, P. R. China.
Chem Commun (Camb). 2017 Feb 28;53(18):2665-2668. doi: 10.1039/c6cc09762f.
The first nBuNI-catalyzed oxidative cross-coupling reaction of carbon dioxide, amines and arylketones has been successfully developed by using TBHP as the oxidant, providing an efficient, atom-economical and metal-free strategy for the synthesis of a range of O-β-oxoalkyl carbamates.
首次成功开发了以叔丁基过氧化氢（TBHP）作为氧化剂，在正丁基异腈（nBuNI）催化下，二氧化碳、胺类与芳基酮的氧化交叉偶联反应，为一系列O-β-氧代烷基氨基甲酸酯的合成提供了一种高效、原子经济且无金属的策略。
