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基于纤维素纳米纤维的磁性生物纳米复合材料:快速、简便且有效的制备方法。

Magnetic bionanocomposites from cellulose nanofibers: Fast, simple and effective production method.

作者信息

Tarrés Quim, Deltell Alexandre, Espinach F Xavier, Pèlach M Àngels, Delgado-Aguilar Marc, Mutjé Pere

机构信息

LEPAMAP Research Group, University of Girona, Maria Aurèlia Capmany, 61, Girona 17003, Spain.

GREFEMA Research Group, University of Girona, Maria Aurèlia Capmany, 61, Girona 17003, Spain.

出版信息

Int J Biol Macromol. 2017 Jun;99:29-36. doi: 10.1016/j.ijbiomac.2017.02.072. Epub 2017 Feb 21.

Abstract

Nanocellulose is becoming a topic of great interest due to its lightweight, huge availability and its interesting properties. Among these properties, it is worthy to distinguish its specific surface and its strength. Both properties allow producing films with great mechanical properties able to retain nanoparticles which can provide the nanopaper of much functionality. Many applications for nanocellulose nanocomposites have been reported, demonstrating the interesting opportunities that this product has in a near future. In this sense, the present work attempts to produce membranes based on cellulose nanofibers (CNF) filled with magnetite nanoparticles with the purpose of developing membranes for loudspeakers. The main advantage of this is the avoiding of the iron core that one can find in any loudspeaker, since the membrane itself acts as that core. Bionanocomposites ranging from 10 to 70% of magnetite nanoparticles were produced by filtration in a nitrocellulose membrane with a pore size of 0,22μm. Tensile tests showed that mechanical properties were decreased as the amount of magnetite was increased. They were observed by FE-SEM to see the interactions between nanoparticles and CNF. Finally, a loudspeaker prototype was developed in order to evaluate the sonorous efficiency of the resulting membranes.

摘要

由于其轻质、大量可得以及有趣的特性,纳米纤维素正成为一个备受关注的话题。在这些特性中,值得一提的是其比表面积和强度。这两个特性使得能够生产出具有优异机械性能的薄膜,这些薄膜能够保留纳米颗粒,从而赋予纳米纸多种功能。已经报道了纳米纤维素纳米复合材料的许多应用,展示了该产品在不久的将来所具有的有趣机遇。从这个意义上讲,目前的工作试图制备基于填充有磁铁矿纳米颗粒的纤维素纳米纤维(CNF)的膜,目的是开发用于扬声器的膜。这样做的主要优点是避免了在任何扬声器中都能找到的铁芯,因为膜本身就起到了铁芯的作用。通过在孔径为0.22μm的硝酸纤维素膜中过滤制备了磁铁矿纳米颗粒含量为10%至70%的生物纳米复合材料。拉伸试验表明,随着磁铁矿含量的增加,机械性能下降。通过场发射扫描电子显微镜(FE-SEM)观察纳米颗粒与CNF之间的相互作用。最后,开发了一个扬声器原型,以评估所得膜的发声效率。

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