Max Planck Institute for Intelligent Systems, Heisenbergstrasse 3, 70569 Stuttgart, Germany.
Kirchhoff Institute for Physics, University of Heidelberg, Im Neuenheimer Feld 227, 69120 Heidelberg, Germany.
Nat Commun. 2017 Feb 24;8:14606. doi: 10.1038/ncomms14606.
Plasmonic colour printing based on engineered metasurfaces has revolutionized colour display science due to its unprecedented subwavelength resolution and high-density optical data storage. However, advanced plasmonic displays with novel functionalities including dynamic multicolour printing, animations, and highly secure encryption have remained in their infancy. Here we demonstrate a dynamic plasmonic colour display technique that enables all the aforementioned functionalities using catalytic magnesium metasurfaces. Controlled hydrogenation and dehydrogenation of the constituent magnesium nanoparticles, which serve as dynamic pixels, allow for plasmonic colour printing, tuning, erasing and restoration of colour. Different dynamic pixels feature distinct colour transformation kinetics, enabling plasmonic animations. Through smart material processing, information encoded on selected pixels, which are indiscernible to both optical and scanning electron microscopies, can only be read out using hydrogen as a decoding key, suggesting a new generation of information encryption and anti-counterfeiting applications.
基于工程化超表面的等离子体颜色打印由于其前所未有的亚波长分辨率和高密度光数据存储,彻底改变了颜色显示科学。然而,具有新颖功能的先进等离子体显示器,包括动态多色打印、动画和高度安全的加密,仍处于起步阶段。在这里,我们展示了一种动态等离子体颜色显示技术,该技术使用催化镁超表面实现了所有上述功能。组成纳米颗粒的镁的受控氢化和脱氢作为动态像素,允许进行等离子体颜色打印、调谐、擦除和颜色恢复。不同的动态像素具有不同的颜色转换动力学,从而实现等离子体动画。通过智能材料处理,仅使用氢作为解码密钥,就可以读取在选定像素上编码的信息,这些像素对于光学和扫描电子显微镜都是不可见的,这表明了新一代信息加密和防伪应用的出现。