乙烯基环丙烷开环的合成应用
Synthetic applications of vinyl cyclopropane opening.
作者信息
Meazza Marta, Guo Hao, Rios Ramon
机构信息
School of Chemistry. University of Southampton. Highfield Campus, SO17 1BJ Southampton, UK.
Department of Chemistry, Fudan University, 220 Handan Road, Shanghai, 200433 Fudan, People's Republic of China.
出版信息
Org Biomol Chem. 2017 Mar 22;15(12):2479-2490. doi: 10.1039/c6ob02647h.
PMID:28233002
Abstract
Vinyl cyclopropanes are amongst the most useful building blocks in organic synthesis. Their easy opening and capacity to generate dipoles have been exploited for the synthesis of cyclopentanes with good yields and sometimes excellent stereoselectivities. In this review we give an overview of their applications, focusing on the present century.
摘要
乙烯基环丙烷是有机合成中最有用的结构单元之一。它们易于开环以及产生偶极的能力已被用于以良好的产率甚至有时是优异的立体选择性合成环戊烷。在本综述中，我们概述了它们的应用，重点是本世纪。
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