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定制分子标签的选择性光解离作为量子光学的一种工具

Selective photodissociation of tailored molecular tags as a tool for quantum optics.

作者信息

Sezer Ugur, Geyer Philipp, Kriegleder Moritz, Debiossac Maxime, Shayeghi Armin, Arndt Markus, Felix Lukas, Mayor Marcel

机构信息

Faculty of Physics, VCQ, University of Vienna, Boltzmanngasse 5, A-1090 Vienna, Austria.

Department of Chemistry, University of Basel, St. Johannsring 19, CH-4056 Basel, Switzerland.

出版信息

Beilstein J Nanotechnol. 2017 Feb 2;8:325-333. doi: 10.3762/bjnano.8.35. eCollection 2017.

Abstract

Recent progress in synthetic chemistry and molecular quantum optics has enabled demonstrations of the quantum mechanical wave-particle duality for complex particles, with masses exceeding 10 kDa. Future experiments with even larger objects will require new optical preparation and manipulation methods that shall profit from the possibility to cleave a well-defined molecular tag from a larger parent molecule. Here we present the design and synthesis of two model compounds as well as evidence for the photoinduced beam depletion in high vacuum in one case.

摘要

合成化学和分子量子光学的最新进展已实现了对质量超过10 kDa的复杂粒子的量子力学波粒二象性的演示。未来对更大物体的实验将需要新的光学制备和操纵方法,这些方法将受益于从更大的母体分子上切割出明确分子标签的可能性。在此,我们展示了两种模型化合物的设计与合成,以及在一种情况下高真空中光致光束耗尽的证据。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a66/5301912/696ae56040ad/Beilstein_J_Nanotechnol-08-325-g002.jpg

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