Department of Microelectronics and Key Laboratory of Artificial Micro- and Nano-structures of Ministry of Education, School of Physics and Technology, Wuhan University , Wuhan 430072, China.
Wuhan National High Magnetic Field Center and School of Optical and Electronic Information, Huazhong University of Science and Technology , Wuhan 430074, China.
ACS Appl Mater Interfaces. 2017 Mar 29;9(12):10798-10804. doi: 10.1021/acsami.6b15275. Epub 2017 Mar 15.
Despite intensive research on improvement in electrical performances of ZnO-based thin-film transistors (TFTs), the instability issues have limited their applications for complementary electronics. Herein, we have investigated the effect of nitrogen and hydrogen (N/H) codoping on the electrical performance and reliability of amorphous InGaZnO (α-IGZO) TFTs. The performance and bias stress stability of α-IGZO device were simultaneously improved by N/H plasma treatment with a high field-effect mobility of 45.3 cm/(V s) and small shifts of threshold voltage (V). On the basis of X-ray photoelectron spectroscopy analysis, the improved electrical performances of α-IGZO TFT should be attributed to the appropriate amount of N/H codoping, which could not only control the V and carrier concentration efficiently, but also passivate the defects such as oxygen vacancy due to the formation of stable Zn-N and N-H bonds. Meanwhile, low-frequency noise analysis indicates that the average trap density near the α-IGZO/SiO interface is reduced by the nitrogen and hydrogen plasma treatment. This method could provide a step toward the development of α-IGZO TFTs for potential applications in next-generation high-definition optoelectronic displays.
尽管对提高基于 ZnO 的薄膜晶体管 (TFT) 的电性能进行了深入研究,但不稳定性问题限制了它们在互补电子学中的应用。在此,我们研究了氮和氢 (N/H) 共掺杂对非晶 InGaZnO (α-IGZO) TFT 的电性能和可靠性的影响。通过 N/H 等离子体处理,同时提高了 α-IGZO 器件的性能和偏置稳定性,具有 45.3 cm/(V s)的高场效应迁移率和较小的阈值电压 (V) 漂移。基于 X 射线光电子能谱分析,α-IGZO TFT 电性能的提高归因于适量的 N/H 共掺杂,这不仅可以有效地控制 V 和载流子浓度,而且由于形成稳定的 Zn-N 和 N-H 键,还可以钝化氧空位等缺陷。同时,低频噪声分析表明,氮和氢等离子体处理降低了 α-IGZO/SiO 界面附近的平均陷阱密度。该方法为开发用于下一代高分辨率光电显示器的 α-IGZO TFT 提供了一个途径。