Muginova Svetlana V, Myasnikova Dina A, Kazarian Sergei G, Shekhovtsova Tatiana N
Analytical Chemistry Division, Department of Chemistry, Lomonosov Moscow State University.
Anal Sci. 2017;33(3):261-274. doi: 10.2116/analsci.33.261.
This paper reviews the primary literature reporting the use of ionic liquids (ILs) in optical sensing technologies. The optical chemical sensors that have been developed with the assistance of ILs are classified according to the type of resultant material. Key aspects of applying ILs in such sensors are revealed and discussed. They include using ILs as solvents for the synthesis of sensor matrix materials; additives in polymer matrices; matrix materials; modifiers of the surfaces; and multifunctional sensor components. The operational principles, design, texture, and analytical characteristics of the offered sensors for determining CO, O, metal ions, CN, and various organic compounds are critically discussed. The key advantages and disadvantages of using ILs in optical sensing technologies are defined. Finally, the applicability of the described materials for chemical analysis is evaluated, and possibilities for their further modernization are outlined.
本文综述了报道离子液体(ILs)在光学传感技术中应用的主要文献。借助离子液体开发的光学化学传感器根据所得材料的类型进行分类。揭示并讨论了在这类传感器中应用离子液体的关键方面。它们包括将离子液体用作合成传感器基质材料的溶剂;聚合物基质中的添加剂;基质材料;表面改性剂;以及多功能传感器组件。对所提供的用于测定一氧化碳、氧气、金属离子、氰化物和各种有机化合物的传感器的工作原理、设计、结构和分析特性进行了批判性讨论。明确了在光学传感技术中使用离子液体的主要优点和缺点。最后,评估了所描述材料在化学分析中的适用性,并概述了其进一步改进的可能性。