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负载有机磷部分的纳米结构碳材料：合成与应用

Nanostructured carbon materials decorated with organophosphorus moieties: synthesis and application.

作者信息

Biagiotti Giacomo, Langè Vittoria, Ligi Cristina, Caporali Stefano, Muniz-Miranda Maurizio, Flis Anna, Pietrusiewicz K Michał, Ghini Giacomo, Brandi Alberto, Cicchi Stefano

机构信息

Dipartimento di Chimica Ugo Schiff Università di Firenze, Via della Lastruccia 3-13, 50019 Sesto Fiorentino, Italy.

Consorzio Interuniversitario Nazionale per la Scienza e Tecnologia di Materiali INSTM, 50123 Firenze, Italy; Istituto dei Sistemi Complessi Consiglio Nazionale delle Ricerche, 50019 Sesto Fiorentino, Italy.

出版信息

Beilstein J Nanotechnol. 2017 Feb 22;8:485-493. doi: 10.3762/bjnano.8.52. eCollection 2017.

DOI:10.3762/bjnano.8.52
PMID:28326239
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5331327/
Abstract

A new synthetic approach for the production of carbon nanomaterials (CNM) decorated with organophosphorus moieties is presented. Three different triphenylphosphine oxide (TPPO) derivatives were used to decorate oxidized multiwalled carbon nanotubes (ox-MWCNTs) and graphene platelets (GPs). The TPPOs chosen bear functional groups able to react with the CNMs by Tour reaction (an amino group), nitrene cycloaddition (an azido group) or CuAAC reaction (one terminal C-C triple bond). All the adducts were characterized by FTIR, Raman spectroscopy, TEM, XPS, elemental analysis and ICP-AES. The cycloaddition of nitrene provided the higher loading on ox-MWCNTs and GPs as well, while the Tour approach gave best results with nanotubes (CNTs). Finally, we investigated the possibility to reduce the TPPO functionalized CNMs to the corresponding phosphine derivatives and applied one of the materials produced as heterogeneous organocatalyst in a Staudinger ligation reaction.

摘要

本文提出了一种制备有机磷修饰的碳纳米材料（CNM）的新合成方法。使用三种不同的三苯基氧化膦（TPPO）衍生物修饰氧化多壁碳纳米管（ox-MWCNT）和石墨烯片（GP）。所选用的TPPO带有能够通过图尔反应（一个氨基）、氮烯环加成（一个叠氮基）或铜催化的炔烃-叠氮环加成反应（一个末端碳-碳三键）与碳纳米材料发生反应的官能团。所有加合物均通过傅里叶变换红外光谱（FTIR）、拉曼光谱、透射电子显微镜（TEM）、X射线光电子能谱（XPS）、元素分析和电感耦合等离子体原子发射光谱（ICP-AES）进行表征。氮烯的环加成反应在ox-MWCNT和GP上也提供了更高的负载量，而图尔方法对纳米管（CNT）的效果最佳。最后，我们研究了将TPPO功能化的碳纳米材料还原为相应膦衍生物的可能性，并将所制备的一种材料用作施陶丁格连接反应中的非均相有机催化剂。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6d34/5331327/d275135aa9a4/Beilstein_J_Nanotechnol-08-485-g011.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6d34/5331327/fa3bc167d5cd/Beilstein_J_Nanotechnol-08-485-g009.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6d34/5331327/59a2ad8d8d51/Beilstein_J_Nanotechnol-08-485-g004.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6d34/5331327/5bf3b19394ca/Beilstein_J_Nanotechnol-08-485-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6d34/5331327/d275135aa9a4/Beilstein_J_Nanotechnol-08-485-g011.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6d34/5331327/ce544a20c715/Beilstein_J_Nanotechnol-08-485-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6d34/5331327/cea7ed0a4198/Beilstein_J_Nanotechnol-08-485-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6d34/5331327/fa3bc167d5cd/Beilstein_J_Nanotechnol-08-485-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6d34/5331327/97e2746838eb/Beilstein_J_Nanotechnol-08-485-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6d34/5331327/59a2ad8d8d51/Beilstein_J_Nanotechnol-08-485-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6d34/5331327/230f396d613f/Beilstein_J_Nanotechnol-08-485-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6d34/5331327/dcc2e15e943f/Beilstein_J_Nanotechnol-08-485-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6d34/5331327/5bf3b19394ca/Beilstein_J_Nanotechnol-08-485-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6d34/5331327/d275135aa9a4/Beilstein_J_Nanotechnol-08-485-g011.jpg

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