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硅烯:锂离子电池的一种有前途的阳极材料。

Silicene: A Promising Anode for Lithium-Ion Batteries.

机构信息

Institute for Superconducting and Electronic Materials, Australian Institute for Innovative Materials, University of Wollongong, Innovation Campus, North Wollongong, New South Wales, 2500, Australia.

Center of Materials Physics and Chemistry, and Department of Physics, Beihang University, Beijing, 100191, P. R. China.

出版信息

Adv Mater. 2017 Dec;29(48). doi: 10.1002/adma.201606716. Epub 2017 Mar 22.

Abstract

Silicene, a single-layer-thick silicon nanosheet with a honeycomb structure, is successfully fabricated by the molecular-beam-epitaxy (MBE) deposition method on metallic substrates and by the solid-state reaction method. Here, recent progress on the features of silicene that make it a prospective anode for lithium-ion batteries (LIBs) are discussed, including its charge-carrier mobility, chemical stability, and metal-silicene interactions. The electrochemical performance of silicene is reviewed in terms of both theoretical predictions and experimental measurements, and finally, its challenges and outlook are considered.

摘要

硅烯是一种单层的硅纳米片,具有蜂窝状结构,通过分子束外延(MBE)沉积法在金属衬底上以及固态反应法成功制备。在此,讨论了硅烯作为锂离子电池(LIB)有前景的阳极的特征,包括其载流子迁移率、化学稳定性和金属-硅烯相互作用。从理论预测和实验测量两个方面综述了硅烯的电化学性能,最后考虑了其挑战和前景。

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