Palomo Jose M, Filice Marco
Departament of Biocatalysis, Institute of Catalysis (CSIC), Marie Curie 2, Cantoblanco, Campus UAM, 28049 Madrid, Spain.
Advanced Imaging Unit, Spanish National Research Center for Cardiovascular Disease (CNIC), 28049 Madrid, Spain.
Nanomaterials (Basel). 2016 May 5;6(5):84. doi: 10.3390/nano6050084.
This review compiles the most recent advances described in literature on the preparation of noble metal nanoparticles induced by biological entities. The use of different free or substituted carbohydrates, peptides, proteins, microorganisms or plants have been successfully applied as a new green concept in the development of innovative strategies to prepare these nanoparticles as different nanostructures with different forms and sizes. As a second part of this review, the application of their synthetic ability as new heterogonous catalysts has been described in C-C bond-forming reactions (as Suzuki, Heck, cycloaddition or multicomponent), oxidations and dynamic kinetic resolutions.
本综述汇编了文献中描述的关于生物实体诱导制备贵金属纳米颗粒的最新进展。不同的游离或取代碳水化合物、肽、蛋白质、微生物或植物已被成功用作一种新的绿色概念，用于开发创新策略，以制备具有不同形状和尺寸的不同纳米结构的这些纳米颗粒。作为本综述的第二部分，已描述了它们作为新型多相催化剂的合成能力在碳-碳键形成反应（如铃木反应、赫克反应、环加成或多组分反应）、氧化反应和动态动力学拆分中的应用。
