镍（II）催化的胺的 N-甲酰化和 N-酰化反应。
Nickel-(II)-Catalyzed N-Formylation and N-Acylation of Amines.
机构信息
Department of Chemistry, Baburaoji Gholap College , Sangvi, Pune 27, India.
出版信息
Org Lett. 2017 Apr 21;19(8):2078-2081. doi: 10.1021/acs.orglett.7b00660. Epub 2017 Apr 4.
PMID:28375017
Abstract
A highly efficient protocol of Ni(II) metal complex, [Ni(quin)], catalyzing N-formylation and N-acylation of amines with moderate to excellent yields, using N,N-dimethylformamide and N,N-dimethylacetamide in the presence of imidazole, is described here. The protocol shows broad substrate scope for aliphatic, aromatic, and heterocyclic amines.
摘要
本文描述了一种高效的 Ni(II)金属配合物[Ni(quin)]催化胺的 N-甲酰化和 N-酰化的反应protocol，使用 N,N-二甲基甲酰胺和 N,N-二甲基乙酰胺，在咪唑的存在下，产率中等至优秀。该 protocol 对脂肪族、芳香族和杂环胺具有广泛的底物适用性。
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