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磁性可回收的二氧化硅包覆铁氧体磁铁矿-K蒙脱石纳米催化剂及其在无溶剂条件下的氧、氮和硫酰化反应中的应用。

Magnetically recyclable silica-coated ferrite magnetite-K montmorillonite nanocatalyst and its applications in O, N, and S-acylation reaction under solvent-free conditions.

作者信息

Tandon Nitin, Patil Shripad M, Tandon Runjhun, Kumar Pushpendra

机构信息

Department of Chemistry, School of Chemical Engineering and Physical Sciences, Lovely Professional University Phagwara-144411 India

出版信息

RSC Adv. 2021 Jun 16;11(35):21291-21300. doi: 10.1039/d1ra02222a. eCollection 2021 Jun 15.

Abstract

Novel silica-coated ferrite nanoparticles supported with montmorillonite (K) have been prepared successfully by using a simple impregnation method. Further, these nanoparticles were characterized by using different analytical methods like FT-IR, PXRD, EDS, and FE-SEM techniques. In addition, these nanoparticles have been explored for their catalytic activity for the O, N, and S-acylation reactions under solvent-free conditions which gave moderate to excellent yields in a much shorter reaction time. Moreover, these nanoparticles could easily be separated out from the reaction medium after the reaction completion by using an external magnetic field and have been re-used for 10 cycles without any significant loss of the catalytic activity.

摘要

通过简单的浸渍法成功制备了负载有蒙脱石(K)的新型二氧化硅包覆铁氧体纳米颗粒。此外,利用傅里叶变换红外光谱(FT-IR)、粉末X射线衍射(PXRD)、能谱分析(EDS)和场发射扫描电子显微镜(FE-SEM)等不同分析方法对这些纳米颗粒进行了表征。此外,还研究了这些纳米颗粒在无溶剂条件下对O、N和S-酰化反应的催化活性,在更短的反应时间内获得了中等至优异的产率。此外,反应完成后,通过外部磁场可以很容易地将这些纳米颗粒从反应介质中分离出来,并已重复使用10次,催化活性没有任何显著损失。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c057/9034005/33e499e03769/d1ra02222a-s1.jpg

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