采用广义数值反演方法分析多核纳米粒子的结构和磁性。

Structural and magnetic properties of multi-core nanoparticles analysed using a generalised numerical inversion method.

机构信息

Department CITIMAC, Faculty of Science, University of Cantabria, 39005 Santander, Spain.

Healthcare Biomagnetics Laboratory, University College London, 21 Albemarle Street, London, W1S 4BS, UK.

出版信息

Sci Rep. 2017 Apr 11;7:45990. doi: 10.1038/srep45990.

Abstract

The structural and magnetic properties of magnetic multi-core particles were determined by numerical inversion of small angle scattering and isothermal magnetisation data. The investigated particles consist of iron oxide nanoparticle cores (9 nm) embedded in poly(styrene) spheres (160 nm). A thorough physical characterisation of the particles included transmission electron microscopy, X-ray diffraction and asymmetrical flow field-flow fractionation. Their structure was ultimately disclosed by an indirect Fourier transform of static light scattering, small angle X-ray scattering and small angle neutron scattering data of the colloidal dispersion. The extracted pair distance distribution functions clearly indicated that the cores were mostly accumulated in the outer surface layers of the poly(styrene) spheres. To investigate the magnetic properties, the isothermal magnetisation curves of the multi-core particles (immobilised and dispersed in water) were analysed. The study stands out by applying the same numerical approach to extract the apparent moment distributions of the particles as for the indirect Fourier transform. It could be shown that the main peak of the apparent moment distributions correlated to the expected intrinsic moment distribution of the cores. Additional peaks were observed which signaled deviations of the isothermal magnetisation behavior from the non-interacting case, indicating weak dipolar interactions.

摘要

通过对小角散射和等温磁化数据进行数值反演,确定了磁性多核粒子的结构和磁性。研究的粒子由嵌入聚苯乙烯球(160nm)中的氧化铁纳米颗粒核(9nm)组成。对粒子进行了全面的物理特性表征,包括透射电子显微镜、X 射线衍射和不对称流场流分离。通过胶体分散的静态光散射、小角 X 射线散射和小角中子散射数据的间接傅里叶变换,最终揭示了它们的结构。提取的对距离分布函数清楚地表明,核主要聚集在聚苯乙烯球的外表面层中。为了研究磁性,分析了多核粒子(固定和分散在水中)的等温磁化曲线。该研究的突出特点是应用相同的数值方法从间接傅里叶变换中提取粒子的表观磁矩分布。结果表明,表观磁矩分布的主峰与核的预期本征磁矩分布相关。观察到额外的峰,表明等温磁化行为偏离非相互作用情况,表明存在弱偶极相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/72cd/5387715/d7f9746fd68f/srep45990-f1.jpg

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