Korea Advanced Nano Fab Center, Suwon, Gyeonggi 16229, Republic of Korea.
Nanotechnology. 2017 Jun 2;28(22):225703. doi: 10.1088/1361-6528/aa6fdd. Epub 2017 Apr 27.
We demonstrated an InGaN/GaN-based, monolithic, white light-emitting diode (LED) without phosphors by using morphology-controlled active layers formed on multi-facet GaN templates containing polar and semipolar surfaces. The nanostructured surface morphology was controlled by changing the growth time, and distinct multiple photoluminescence peaks were observed at 360, 460, and 560 nm; these features were caused by InGaN/GaN-based multiple quantum wells (MQWs) on the nanostructured facets. The origin of each multi-peak was related to the different indium (In) compositions in the different planes of the quantum wells grown on the nanostructured GaN. The emitting units of MQWs in the LED structures were continuously connected, which is different from other GaN-based nanorod or nanowire LEDs. Therefore, the suggested structure had a larger active area. From the electroluminescence spectrum of the fabricated LED, monolithic white light emission with CIE color coordinates of x = 0.306 and y = 0.333 was achieved via multi-facet control combined with morphology control of the metal organic chemical vapor deposition-selective area growth of InGaN/GaN MQWs.
我们通过使用在包含极性和半极性表面的多面 GaN 模板上形成的形态控制有源层,展示了一种无荧光粉的基于 InGaN/GaN 的单片白光发光二极管 (LED)。通过改变生长时间来控制纳米结构表面形态,并在 360、460 和 560nm 处观察到明显的多个光致发光峰;这些特征是由纳米结构化晶面的基于 InGaN/GaN 的多量子阱 (MQW) 引起的。每个多峰的起源与在纳米结构化 GaN 上生长的量子阱的不同平面中的不同铟 (In) 组成有关。LED 结构中的 MQW 的发射单元连续连接,这与其他基于 GaN 的纳米棒或纳米线 LED 不同。因此,所提出的结构具有更大的有源区。从所制造的 LED 的电致发光光谱中,通过多晶面控制与 InGaN/GaN MQW 的金属有机化学气相沉积-选择区域生长的形态控制相结合,实现了 CIE 颜色坐标为 x = 0.306 和 y = 0.333 的单片白光发射。