School of Materials Science and Engineering, Georgia Institute of Technology , Atlanta, Georgia 30332-0245, United States.
Laboratory of Nanophotonic Functional Materials and Devices, Institute of Optoelectronic Materials and Technology, South China Normal University , Guangzhou, China 510631.
Nano Lett. 2017 Jun 14;17(6):3718-3724. doi: 10.1021/acs.nanolett.7b01004. Epub 2017 May 16.
Achievement of p-n homojuncted GaN enables the birth of III-nitride light emitters. Owing to the wurtzite-structure of GaN, piezoelectric polarization charges present at the interface can effectively control/tune the optoelectric behaviors of local charge-carriers (i.e., the piezo-phototronic effect). Here, we demonstrate the significantly enhanced light-output efficiency and suppressed efficiency droop in GaN microwire (MW)-based p-n junction ultraviolet light-emitting diode (UV LED) by the piezo-phototronic effect. By applying a -0.12% static compressive strain perpendicular to the p-n junction interface, the relative external quantum efficiency of the LED is enhanced by over 600%. Furthermore, efficiency droop is markedly reduced from 46.6% to 7.5% and corresponding droop onset current density shifts from 10 to 26.7 A cm. Enhanced electrons confinement and improved holes injection efficiency by the piezo-phototronic effect are revealed and theoretically confirmed as the physical mechanisms. This study offers an unconventional path to develop high efficiency, strong brightness and high power III-nitride light sources.
实现 p-n 同质结 GaN 使 III 族氮化物发光器件得以问世。由于 GaN 的纤锌矿结构,界面处存在的压电极化电荷可以有效地控制/调节局部载流子的光电行为(即压光电效应)。在这里,我们通过压光电效应证明了 GaN 微线(MW)基 p-n 结紫外发光二极管(UV LED)的光输出效率显著提高,效率衰减得到抑制。通过施加垂直于 p-n 结界面的-0.12%的静态压缩应变,LED 的相对外量子效率提高了超过 600%。此外,效率衰减从 46.6%显著降低到 7.5%,相应的衰减起始电流密度从 10 A cm 降低到 26.7 A cm。压光电效应增强了电子限制并提高了空穴注入效率,这被揭示并从理论上得到证实,这是其物理机制。本研究为开发高效率、高亮度和高功率 III 族氮化物光源提供了一条非传统的途径。