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通过压光电子效应提高 InGaN/GaN 多量子阱太阳能电池的转换效率。

Enhanced Solar Cell Conversion Efficiency of InGaN/GaN Multiple Quantum Wells by Piezo-Phototronic Effect.

机构信息

Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Sciences , Beijing 100083, China.

CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology (NCNST) , Beijing 100190, China.

出版信息

ACS Nano. 2017 Sep 26;11(9):9405-9412. doi: 10.1021/acsnano.7b04935. Epub 2017 Sep 8.

Abstract

The piezo-phototronic effect is the tuning of piezoelectric polarization charges at the interface to largely enhance the efficiency of optoelectronic processes related to carrier separation or recombination. Here, we demonstrated the enhanced short-circuit current density and the conversion efficiency of InGaN/GaN multiple quantum well solar cells with an external stress applied on the device. The external-stress-induced piezoelectric charges generated at the interfaces of InGaN and GaN compensate the piezoelectric charges induced by lattice mismatch stress in the InGaN wells. The energy band realignment is calculated with a self-consistent numerical model to clarify the enhancement mechanism of optical-generated carriers. This research not only theoretically and experimentally proves the piezo-phototronic effect modulated the quantum photovoltaic device but also provides a great promise to maximize the use of solar energy in the current energy revolution.

摘要

压电 - 光致电子效应是通过调整界面处的压电极化电荷,从而极大地提高与载流子分离或复合相关的光电过程的效率。在这里,我们通过在器件上施加外部应力,证明了可以增强具有 InGaN/GaN 多量子阱的太阳能电池的短路电流密度和转换效率。在 InGaN 和 GaN 的界面处产生的外部应力诱导的压电电荷补偿了 InGaN 阱中晶格失配应力引起的压电电荷。通过自洽数值模型计算能带重新排列,以阐明光生载流子增强的机制。这项研究不仅从理论和实验上证明了压电 - 光致电子效应可以调制量子光伏器件,而且为最大限度地利用当前能源革命中的太阳能提供了巨大的前景。

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