School of Material Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332-0245, United States.
Nano Lett. 2012 Jul 11;12(7):3851-6. doi: 10.1021/nl301879f. Epub 2012 Jun 20.
We present that the electroluminescence (EL) properties of Mg-doped p-type GaN thin films can be tuned by the piezo-phototronic effect via adjusting the minority carrier injection efficiency at the metal-semiconductor (M-S) interface by strain induced polarization charges. The device is a metal-semiconductor-metal structure of indium tin oxide (ITO)-GaN-ITO. Under different straining conditions, the changing trend of the transport properties of GaN films can be divided into two types, corresponding to the different c-axis orientations of the films. An extreme value was observed for the integral EL intensity under certain applied strain due to the adjusted minority carrier injection efficiency by piezoelectric charges introduced at the M-S interface. The external quantum efficiency of the blue EL at 430 nm was changed by 5.84% under different straining conditions, which is 1 order of magnitude larger than the change of the green peak at 540 nm. The results indicate that the piezo-phototronic effect has a larger impact on the shallow acceptor states related EL process than on the one related to the deep acceptor states in p-type GaN films. This study has great significance on the practical applications of GaN in optoelectronic devices under a working environment where mechanical deformation is unavoidable such as for flexible/printable light emitting diodes.
我们提出,通过在金属-半导体(M-S)界面处的应变诱导极化电荷来调整少数载流子注入效率,可以通过压光电效应来调节 Mg 掺杂的 p 型 GaN 薄膜的电致发光(EL)性质。该器件是铟锡氧化物(ITO)-GaN-ITO 的金属-半导体-金属结构。在不同的应变条件下,GaN 薄膜的输运性质的变化趋势可以分为两种类型,这对应于薄膜的不同 c 轴取向。由于在 M-S 界面处引入的压电电荷调整了少数载流子注入效率,因此在一定的外加应变下,整体 EL 强度观察到极值。在不同的应变条件下,430nm 处的蓝色 EL 的外量子效率变化了 5.84%,这比 540nm 处的绿光峰值变化大 1 个数量级。结果表明,压光电效应对 p 型 GaN 薄膜中与浅受主态相关的 EL 过程的影响比与深受主态相关的 EL 过程的影响更大。这项研究对于 GaN 在工作环境中不可避免地发生机械变形的光电设备中的实际应用具有重要意义,例如柔性/可打印发光二极管。