以亲电N-F试剂为氧化剂的亲电硒催化作用。
Electrophilic Selenium Catalysis with Electrophilic N-F Reagents as the Oxidants.
作者信息
Guo Ruizhi, Liao Lihao, Zhao Xiaodan
机构信息
Institute of Organic Chemistry & MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, China.
出版信息
Molecules. 2017 May 19;22(5):835. doi: 10.3390/molecules22050835.
A suitable oxidative system is crucial to electrophilic selenium catalysis (ESC). This short review offers the overview of recent development in ESC with electrophilic N-F reagents as the oxidants. Several highly selective transformations of alkenes such as allylic or vinylic imidation, pyridination, -dichlorination, oxidative cyclization and asymmetric cyclization have been described.
合适的氧化体系对于亲电硒催化（ESC）至关重要。本综述概述了以亲电N-F试剂作为氧化剂的亲电硒催化的最新进展。已描述了烯烃的几种高选择性转化，如烯丙基或乙烯基亚胺化、吡啶化、二氯化、氧化环化和不对称环化。
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