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喷雾法显现汗潜指纹的红色荧光碳点:干燥过程中的咖啡环效应与未猝灭的荧光。

Red-Emissive Carbon Dots for Fingerprints Detection by Spray Method: Coffee Ring Effect and Unquenched Fluorescence in Drying Process.

机构信息

Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University , Shanghai 200433, P. R. China.

出版信息

ACS Appl Mater Interfaces. 2017 Jun 7;9(22):18429-18433. doi: 10.1021/acsami.7b03917. Epub 2017 May 24.


DOI:10.1021/acsami.7b03917
PMID:28537370
Abstract

Brightly red fluorescent carbon dots are synthesized hydrothermally and dissolved in diluted hydrochloric acid solution. Such carbon dots exhibit excitation-independent emission at about 620 nm with quantum yield over 10%, which is visible in daylight. After the carbon dots solution is sprayed to the fingerprints on various solid substrates and dried in air, clear fingerprints can be seen under an ultraviolet lamp and stay stable for 1 day. Detailed characterizations suggest that during the drying process, the coffee-ring effect and the electrostatic interactions between the carbon dots and the fingerprint residues prevent the typical aggregation-induced fluorescence quenching of carbon dots.

摘要

明亮的红色荧光碳点通过水热法合成,并溶解在稀释的盐酸溶液中。这种碳点在大约 620nm 处表现出与激发无关的发射,量子产率超过 10%,在日光下可见。将碳点溶液喷洒到各种固体基底上的指纹上,然后在空气中干燥后,在紫外灯下可以看到清晰的指纹,并且可以稳定 1 天。详细的特性表明,在干燥过程中,咖啡环效应和碳点与指纹残留物之间的静电相互作用阻止了碳点典型的聚集诱导荧光猝灭。

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Red-Emissive Carbon Dots for Fingerprints Detection by Spray Method: Coffee Ring Effect and Unquenched Fluorescence in Drying Process.

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[3]
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J Fluoresc. 2024-12-12

[4]
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[5]
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[6]
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[7]
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J Fluoresc. 2025-2

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PLoS One. 2024

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[10]
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