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应变石墨烯和其他应变二维材料的电子和光学性质:综述。

Electronic and optical properties of strained graphene and other strained 2D materials: a review.

机构信息

Depto. de Sistemas Complejos, Instituto de Física, Universidad Nacional Autónoma de México, Apdo. Postal 20-364, Mexico City 01000, Mexico.

出版信息

Rep Prog Phys. 2017 Sep;80(9):096501. doi: 10.1088/1361-6633/aa74ef. Epub 2017 May 25.

DOI:10.1088/1361-6633/aa74ef
PMID:28540862
Abstract

This review presents the state of the art in strain and ripple-induced effects on the electronic and optical properties of graphene. It starts by providing the crystallographic description of mechanical deformations, as well as the diffraction pattern for different kinds of representative deformation fields. Then, the focus turns to the unique elastic properties of graphene, and to how strain is produced. Thereafter, various theoretical approaches used to study the electronic properties of strained graphene are examined, discussing the advantages of each. These approaches provide a platform to describe exotic properties, such as a fractal spectrum related with quasicrystals, a mixed Dirac-Schrödinger behavior, emergent gravity, topological insulator states, in molecular graphene and other 2D discrete lattices. The physical consequences of strain on the optical properties are reviewed next, with a focus on the Raman spectrum. At the same time, recent advances to tune the optical conductivity of graphene by strain engineering are given, which open new paths in device applications. Finally, a brief review of strain effects in multilayered graphene and other promising 2D materials like silicene and materials based on other group-IV elements, phosphorene, dichalcogenide- and monochalcogenide-monolayers is presented, with a brief discussion of interplays among strain, thermal effects, and illumination in the latter material family.

摘要

这篇综述介绍了应变和波纹效应对石墨烯电子和光学性质的最新研究进展。首先,提供了机械变形的晶体描述以及不同类型代表性变形场的衍射图案。然后,重点介绍了石墨烯独特的弹性性质以及应变的产生方式。接着,研究了用于研究应变石墨烯电子性质的各种理论方法,讨论了每种方法的优点。这些方法为描述奇异性质提供了平台,例如与准晶体相关的分形谱、混合狄拉克-薛定谔行为、新兴引力、拓扑绝缘体状态、分子石墨烯和其他二维离散晶格。接下来,回顾了应变对光学性质的物理影响,重点介绍了拉曼光谱。同时,还介绍了通过应变工程来调整石墨烯光学电导率的最新进展,这为器件应用开辟了新途径。最后,简要回顾了多层石墨烯和其他有前途的二维材料(如硅烯和基于其他 IV 族元素的材料、磷烯、二硫化物和单硫化物单层)中的应变效应,并简要讨论了后一类材料中应变、热效应和光照之间的相互作用。

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