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生物质垃圾制取合成天然气及联产电力过程中化学未反应气体回收的热力学性能

Thermodynamic performance of SNG and power coproduction from MSW with recovery of chemical unreacted gas.

机构信息

Institute of Engineering Thermophysics, Chinese Academy of Sciences, Beijing 100190, PR China; University of Chinese Academy of Sciences, Beijing 100049, PR China.

Institute of Engineering Thermophysics, Chinese Academy of Sciences, Beijing 100190, PR China.

出版信息

Waste Manag. 2017 Sep;67:163-170. doi: 10.1016/j.wasman.2017.05.031. Epub 2017 Jun 3.

Abstract

A cogeneration system for simultaneously producing synthetic natural gas (SNG) and electric power from municipal solid waste (MSW) is developed. This process provides a disposal method for MSW that is environmentally sustainable and uses as an alternative energy sources. Rather than converting all of the synthesis gas into end products, in the proposed system the unconverted gas is recovered for power generation in a combined-cycle unit. The overall efficiency of the proposed system is 36.33%. The energy efficiency of this system is approximately 8.7% higher than that of a standalone SNG production system, and 15.02% higher than that of an MSW incineration system. A sensitivity analysis shows that by increasing the H/CO ratio (α), SNG production and SNG conversion efficiency can be increased, but the overall efficiency does not increase. Increasing the recycling ratio of the unconverted gas (Ru) benefits for the SNG yield up to a value before Ru/(Ru+1)=0.7, and the overall system efficiency reaches its maximum value at Ru/(Ru+1)=0.9. Therefore, partial recycling of the unreacted gas is more efficient up to a point, and higher recycling ratios are less efficient.

摘要

从城市固体废物(MSW)中同时生产合成天然气(SNG)和电力的联产系统。该工艺为 MSW 提供了一种环境可持续的处理方法,并将其作为替代能源。在所提出的系统中,未转化的气体不是全部转化为最终产品,而是回收用于联合循环单元的发电。所提出系统的整体效率为 36.33%。该系统的能源效率比独立的 SNG 生产系统高约 8.7%,比 MSW 焚烧系统高 15.02%。敏感性分析表明,通过增加 H/CO 比(α),可以提高 SNG 产量和 SNG 转化效率,但整体效率不会增加。增加未转化气体的循环比(Ru)有利于 SNG 产量,直到 Ru/(Ru+1)=0.7 为止,并且在 Ru/(Ru+1)=0.9 时达到系统效率的最大值。因此,在一定程度上,部分回收未反应的气体更有效,而更高的回收比效率较低。

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