Department of Chemical Engineering and Biotechnology, National Taipei University of Technology, No. 1, Section 3, Chung-Hsiao East Road, Taipei 106, Taiwan, ROC.
Department of Chemical Engineering and Biotechnology, National Taipei University of Technology, No. 1, Section 3, Chung-Hsiao East Road, Taipei 106, Taiwan, ROC.
J Colloid Interface Sci. 2017 Oct 15;504:626-632. doi: 10.1016/j.jcis.2017.03.039. Epub 2017 Mar 9.
Herein, we report the synthesis of Vanadium Pentoxide Nanoflakes (VO NF) using ionic liquid and employed the VO NF in electrochemical determination of Morin (MR) in fruit samples. The VO NF were characterized by Powder X-ray diffraction (PXRD), scanning electron microscope (SEM), energy-dispersive X-ray analyzer (EDX), differential pulse voltammetry (DPV), and cyclic voltammetry (CV). Remarkably, the as-synthesized VO NF exhibited excellent electrochemical behavior and electrochemical ability towards MR. The CV and DPV studies were recognized that the electrochemical performance of VO NF film modified glassy carbon electrode (VO NF/GCE) towards detection of MR is outstanding in comparison with unmodified GCE. The proposed MR sensor shows a wide linear range, high sensitivity, and low limit of detection are 0.05-10.93μm, 1.130μAμMcm, and 9nM respectively. The fabulous analytical parameters of the developed sensor surpassed the previously reported modified electrodes, rendering the potential application of VO NF in environmental, biomedical, and pharmaceutical samples.
在此,我们报告了使用离子液体合成五氧化二钒纳米片(VO NF),并将 VO NF 用于水果样品中桑色素(MR)的电化学测定。通过粉末 X 射线衍射(PXRD)、扫描电子显微镜(SEM)、能谱(EDX)、差分脉冲伏安法(DPV)和循环伏安法(CV)对 VO NF 进行了表征。值得注意的是,合成的 VO NF 表现出优异的电化学行为和电化学能力,对 MR 具有优异的响应。CV 和 DPV 研究表明,与未修饰的 GCE 相比,VO NF 修饰的玻碳电极(VO NF/GCE)对 MR 的电化学性能具有出色的检测性能。所提出的 MR 传感器具有宽线性范围、高灵敏度和低检测限,分别为 0.05-10.93μm、1.130μAμMcm 和 9nM。与之前报道的修饰电极相比,开发的传感器具有出色的分析参数,这使得 VO NF 在环境、生物医学和制药样品中的潜在应用成为可能。