Applied Organic Chemistry Group, Chemical Science and Technology Division, CSIR-North East Institute of Science and Technology , Jorhat 785006, India.
Academy of Scientific and Innovative Research, CSIR , New Delhi, Delhi 110020, India.
J Org Chem. 2017 Aug 4;82(15):8309-8316. doi: 10.1021/acs.joc.7b01427. Epub 2017 Jul 14.
A synthetic strategy has been developed for the synthesis of 1-azaanthraquinones. This synthetic protocol consists of sequential Pd-catalyzed carbon-nitrogen bond formation followed by Lewis acid catalyzed intramolecular cyclization. The Pd-catalyzed aminated intermediate was isolated and characterized. This sequential reactions strategy provides a wide range of 1-azaanthraquinones with good yields.
已开发出一种用于合成 1-氮杂蒽醌的合成策略。该合成方案包括顺序 Pd 催化的碳-氮键形成，然后是路易斯酸催化的分子内环化。分离并表征了 Pd 催化的氨基化中间体。这种顺序反应策略可提供具有良好收率的广泛的 1-氮杂蒽醌。
