一种用于（-）-戈尼米汀全合成的费歇尔吲哚合成策略。
A FISCHER INDOLIZATION STRATEGY TOWARD THE TOTAL SYNTHESIS OF (-)-GONIOMITINE.
作者信息
Pritchett Beau P, Kikuchi Jun, Numajiri Yoshitaka, Stoltz Brian M
机构信息
The Warren and Katharine Schlinger Laboratory for Chemistry and Chemical Engineering, Division of Chemistry and Chemical Engineering, California Institute of Technology, 1200 East California Blvd. MC101-20, Pasadena, CA 91125 (USA).
出版信息
Heterocycles. 2017;95(2):1245-1253. doi: 10.3987/COM-16-S(S)80. Epub 2017 Feb 15.
Abstract
A Fischer indolization strategy toward the core of (-)-goniomitine is reported. Initial investigations into the Pd-catalyzed asymmetric allylic alkylation of dihydropyrido[1,2-]indolone (DHPI) substrates are also discussed.
摘要
报道了一种用于合成（-）-戈尼米汀核心结构的费歇尔吲哚合成策略。还讨论了对二氢吡啶并[1,2 -]吲哚酮（DHPI）底物的钯催化不对称烯丙基烷基化的初步研究。
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