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能够将局部短暂信号转化为全局宏观响应的聚合材料。

Polymeric materials that convert local fleeting signals into global macroscopic responses.

作者信息

Kim Hyungwoo, Baker Matthew S, Phillips Scott T

机构信息

Department of Chemistry , The Pennsylvania State University , 104 Chemistry Building , University Park , PA 16802 , USA . Email:

出版信息

Chem Sci. 2015 Jun 1;6(6):3388-3392. doi: 10.1039/c5sc00701a. Epub 2015 Apr 9.

DOI:10.1039/c5sc00701a
PMID:28706703
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5490430/
Abstract

We report a general design strategy for creating polymeric materials that are capable of providing global, macroscopic changes in their properties in response to specific local and fleeting stimuli. In a proof-of-concept demonstration, a single polymer is used, yet it enables selective responses to specific stimuli, and then internally drives a macroscopic change in the material (even in locations not exposed to the stimulus), where the magnitude of change is independent of the intensity of the applied stimulus.

摘要

我们报告了一种用于创建聚合物材料的通用设计策略,该材料能够响应特定的局部短暂刺激,在其性能上产生整体的宏观变化。在一个概念验证演示中,使用了单一聚合物,但它能够对特定刺激产生选择性响应,然后在材料内部驱动宏观变化(即使在未暴露于刺激的位置),变化的幅度与所施加刺激的强度无关。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9119/5490430/06465056c9df/c5sc00701a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9119/5490430/47edd5b6fe2d/c5sc00701a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9119/5490430/0163d509f9d8/c5sc00701a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9119/5490430/06465056c9df/c5sc00701a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9119/5490430/47edd5b6fe2d/c5sc00701a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9119/5490430/0163d509f9d8/c5sc00701a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9119/5490430/06465056c9df/c5sc00701a-f3.jpg

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