Nanotechnology. 2017 Sep 27;28(39):395202. doi: 10.1088/1361-6528/aa8013. Epub 2017 Jul 18.
Resistance switching devices, whose operation is driven by formation (SET) and dissolution (RESET) of conductive paths shorting and disconnecting the two metal electrodes, have recently received great attention and a deep general comprehension of their operation has been achieved. However, the link between switching characteristics and material properties is still quite weak. In particular, doping of the switching oxide layer has often been investigated only for looking at performance upgrade and rarely for a meticulous investigation of the switching mechanism. In this paper, the impact of Al doping of HfO devices on their switching operations, retention loss mechanisms and random telegraph noise traces is investigated. In addition, phenomenological modeling of the switching operation is performed for device employing both undoped and doped HfO. We demonstrate that Al doping influences the filament disruption process during the RESET operation and, in particular, it contributes in preventing an efficient restoration of the oxide with respect to undoped devices.
阻变器件的工作原理是通过形成(SET)和消除(RESET)短接和断开两个金属电极的导电通路来实现的,最近受到了极大的关注,并且对其工作原理有了深入的普遍理解。然而,开关特性与材料特性之间的联系仍然相当薄弱。特别是,对开关氧化物层的掺杂通常仅用于提高性能,很少用于对开关机制进行细致的研究。在本文中,研究了 Al 掺杂对 HfO 器件的开关操作、保持损耗机制和随机电报噪声迹线的影响。此外,还对采用未掺杂和掺杂 HfO 的器件进行了开关操作的唯象建模。我们证明,Al 掺杂会影响 RESET 操作过程中的细丝中断过程,特别是它有助于防止与未掺杂器件相比,氧化物的有效恢复。