Division of Advanced Materials Engineering & Research Center of Advanced Materials Development, Chonbuk National University, Jeonju, 54896, Republic of Korea.
Korea Photonics Technology Institute, Gwangju, 61007, Republic of Korea.
Sci Rep. 2017 Aug 2;7(1):7164. doi: 10.1038/s41598-017-07808-2.
We report a phosphor-free white light-emitting diodes (LED) realized by the monolithic integration of InGaN/GaN (438 nm, blue), InGaN/GaN (513 nm, green), and InGaN/InGaN (602 nm, red) quantum wells (QWs) as an active medium. The QWs corresponding to blue and green light were grown using a conventional growth mode. For the red spectral emission, five-stacked InGaN/InGaN QWs were realized by the so-called Ga-flow-interruption (Ga-FI) technique, wherein the Ga supply was periodically interrupted during the deposition of InGaN to form an InGaN well. The vertical and lateral distributions of the three different light emissions were investigated by fluorescence microscope (FM) images. The FM image measured at a focal point in the middle of the n-GaN cladding layer for the red-emitting LED shows that light emissions with flower-like patterns with six petals are periodically observed. The chromaticity coordinates of the electroluminescence spectrum for the white LEDs at an injection current of 80 mA are measured to be (0.316, 0.312), which is close to ideal white light. In contrast with phosphor-free white-light-emitting devices based on nanostructures, our white light device exhibits a mixture of three independent wavelengths by monolithically grown InGaN-based QWs, thus demonstrating a more facile technique to obtain white LEDs.
我们报道了一种通过单片集成 InGaN/GaN(438nm,蓝色)、InGaN/GaN(513nm,绿色)和 InGaN/InGaN(602nm,红色)量子阱(QW)实现的无磷白光发光二极管(LED),其中 QW 作为有源介质。对应于蓝光和绿光的 QW 采用常规生长模式生长。对于红光光谱发射,通过所谓的 Ga 流中断(Ga-FI)技术实现了五层 InGaN/InGaN QW,其中在沉积 InGaN 期间周期性地中断 Ga 供应以形成 InGaN 阱。通过荧光显微镜(FM)图像研究了三种不同光发射的垂直和横向分布。对于红色发光 LED,在 n-GaN 包层层中间焦点处测量的 FM 图像表明,周期性地观察到具有六个花瓣的花状图案的光发射。在 80mA 注入电流下,白光 LED 的电致发光光谱的色度坐标测量为(0.316,0.312),接近理想白光。与基于纳米结构的无磷白光发光器件相比,我们的白光器件通过单片生长的 InGaN 基 QW 显示出三种独立波长的混合物,从而展示了一种更简单的技术来获得白光 LED。