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用于高温和恶劣环境应用的γ-Al₂O₃上电沉积铂膜的Ti、Cr、W、Ta和Pt作为籽晶层的性能研究。

Capability Study of Ti, Cr, W, Ta and Pt as Seed Layers for Electrodeposited Platinum Films on γ-Al₂O₃ for High Temperature and Harsh Environment Applications.

作者信息

Seifert Marietta, Brachmann Erik, Rane Gayatri K, Menzel Siegfried B, Gemming Thomas

机构信息

SAWLab Saxony, IFW Dresden, P.O. Box 270116, 01171 Dresden, Germany.

出版信息

Materials (Basel). 2017 Jan 11;10(1):54. doi: 10.3390/ma10010054.

DOI:10.3390/ma10010054
PMID:28772415
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5344629/
Abstract

High temperature surface acoustic wave sensors based on radio frequency identification technology require adequate antennas of high efficiency and thermal stability for the signal transmission. Platinum is well known and frequently used as a material of choice for high temperature and harsh environment applications because of the high melting point and its chemical stability. Therefore, one way to realize high temperature stable antennas is the combination of a Pt metallization on an Al 2 O 3 substrate. As a cost-effective technique, the Pt film is deposited via electrochemical deposition. For this growth procedure, a pre-deposited metallization on the Al 2 O 3 layer is required. This paper analyzes the influence of various seed layers (Ta, Ti, W, Cr, Pt) on the morphology, stability and electrical properties of the electrochemically-grown Pt thick film after heat treatments up to 1000 ∘ C in air. We find an oxidation of all adhesion layers except for Pt, for which the best electrical properties were measured. Although significant areas of the films delaminate from the substrate, individual anchor structures retain a stable connection between the Pt layer and the rough Al 2 O 3 substrate.

摘要

基于射频识别技术的高温表面声波传感器需要高效且热稳定的天线来进行信号传输。铂因其高熔点和化学稳定性,是高温及恶劣环境应用中广为人知且常用的首选材料。因此,实现高温稳定天线的一种方法是在氧化铝衬底上进行铂金属化处理。作为一种经济高效的技术,铂膜通过电化学沉积来制备。对于这种生长过程,需要在氧化铝层上预先沉积金属化层。本文分析了在空气中加热至1000℃后,各种种子层(钽、钛、钨、铬、铂)对电化学生长的铂厚膜的形貌、稳定性和电学性能的影响。我们发现除铂之外的所有粘附层都会发生氧化,而铂层的电学性能最佳。尽管膜的大片区域从衬底上分层,但单个锚固结构在铂层和粗糙的氧化铝衬底之间保持着稳定的连接。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/802d1aa451d4/materials-10-00054-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/4f4fd1475072/materials-10-00054-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/8173678f0608/materials-10-00054-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/c3ffead1b6c9/materials-10-00054-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/afa7847e82dc/materials-10-00054-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/90ecc847b419/materials-10-00054-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/e70c87f0044b/materials-10-00054-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/b40fc9f04ff8/materials-10-00054-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/c7c6a1d142e0/materials-10-00054-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/ee77f098ff02/materials-10-00054-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/32cce3cc84e3/materials-10-00054-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/4ba3492c9ced/materials-10-00054-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/fe58e49f0539/materials-10-00054-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/be328e4370b8/materials-10-00054-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/a13f8b79dc2c/materials-10-00054-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/802d1aa451d4/materials-10-00054-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/4f4fd1475072/materials-10-00054-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/8173678f0608/materials-10-00054-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/c3ffead1b6c9/materials-10-00054-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/afa7847e82dc/materials-10-00054-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/90ecc847b419/materials-10-00054-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/e70c87f0044b/materials-10-00054-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/b40fc9f04ff8/materials-10-00054-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/c7c6a1d142e0/materials-10-00054-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/ee77f098ff02/materials-10-00054-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/32cce3cc84e3/materials-10-00054-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/4ba3492c9ced/materials-10-00054-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/fe58e49f0539/materials-10-00054-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/be328e4370b8/materials-10-00054-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/a13f8b79dc2c/materials-10-00054-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eefb/5344629/802d1aa451d4/materials-10-00054-g015.jpg

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