Venditti Iole
Department of Chemistry, Sapienza University of Rome, Piazzale Aldo Moro 5, 00187 Rome, Italy.
Materials (Basel). 2017 Jan 24;10(2):97. doi: 10.3390/ma10020097.
This review concerns the recently emerged class of composite colloidal photonic crystals (PCs), in which gold nanoparticles (AuNPs) are included in the photonic structure. The use of composites allows achieving a strong modification of the optical properties of photonic crystals by involving the light scattering with electronic excitations of the gold component (surface plasmon resonance, SPR) realizing a combination of absorption bands with the diffraction resonances occurring in the body of the photonic crystals. Considering different preparations of composite plasmonic-photonic crystals, based on 3D-PCs in presence of AuNPs, different resonance phenomena determine the optical response of hybrid crystals leading to a broadly tunable functionality of these crystals. Several chemical methods for fabrication of opals and inverse opals are presented together with preparations of composites plasmonic-photonic crystals: the influence of SPR on the optical properties of PCs is also discussed. Main applications of this new class of composite materials are illustrated with the aim to offer the reader an overview of the recent advances in this field.
本综述涉及最近出现的一类复合胶体光子晶体(PCs),其中光子结构中包含金纳米颗粒(AuNPs)。复合材料的使用能够通过使光与金组分的电子激发(表面等离子体共振,SPR)发生光散射,实现吸收带与光子晶体体内发生的衍射共振相结合,从而对光子晶体的光学性质进行强烈改性。考虑到基于存在AuNPs的三维光子晶体的复合等离子体光子晶体的不同制备方法,不同的共振现象决定了混合晶体的光学响应,从而导致这些晶体具有广泛可调谐的功能。文中介绍了几种制备蛋白石和反蛋白石的化学方法以及复合等离子体光子晶体的制备方法:还讨论了SPR对光子晶体光学性质的影响。本文展示了这类新型复合材料的主要应用,旨在让读者了解该领域的最新进展。