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用于数字压花应用的大豆油基聚氨酯的制备与表征

Preparation and Characterization of Soybean Oil-Based Polyurethanes for Digital Doming Applications.

作者信息

Pantone Vincenzo, Laurenza Amelita Grazia, Annese Cosimo, Comparelli Roberto, Fracassi Francesco, Fini Paola, Nacci Angelo, Russo Antonella, Fusco Caterina, D'Accolti Lucia

机构信息

Greenswitch s.r.l., 71013 Ferrandina (MT), Italy.

Dipartimento di Chimica, Università di Bari "A. Moro", Via Orabona 4, 70126 Bari, Italy.

出版信息

Materials (Basel). 2017 Jul 25;10(8):848. doi: 10.3390/ma10080848.

DOI:10.3390/ma10080848
PMID:28773208
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5578214/
Abstract

Polyurethane-resin doming is currently one of the fastest growing markets in the field of industrial graphics and product identification. Semi-rigid bio-based polyurethanes were prepared deriving from soybean oil as a valuable alternative to fossil materials for digital doming and applied to digital mosaic technology. Bio-resins produced can favorably compete with the analogous fossil polymers, giving high-quality surface coatings (ascertained by SEM analyses). In addition, polyurethane synthesis was accomplished by using a mercury- and tin-free catalyst (the commercially available zinc derivative K22) bringing significant benefits in terms of cost efficiency and eco-sustainability.

摘要

聚氨酯树脂隆起成型目前是工业图形和产品标识领域中增长最快的市场之一。以大豆油为原料制备了半刚性生物基聚氨酯，作为数字隆起成型中化石材料的一种有价值的替代品，并应用于数字镶嵌技术。所生产的生物树脂能够与类似的化石聚合物形成有力竞争，可提供高质量的表面涂层（通过扫描电子显微镜分析确定）。此外，聚氨酯合成采用了无汞和无锡催化剂（市售的锌衍生物K22），在成本效益和生态可持续性方面带来了显著优势。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a053/5578214/68f3f3151c8a/materials-10-00848-g012.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a053/5578214/54660e4c6284/materials-10-00848-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a053/5578214/68f3f3151c8a/materials-10-00848-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a053/5578214/00003f194ae3/materials-10-00848-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a053/5578214/c474f3b33ea9/materials-10-00848-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a053/5578214/70b769a3692a/materials-10-00848-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a053/5578214/f30f94034b45/materials-10-00848-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a053/5578214/0b8c249948a7/materials-10-00848-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a053/5578214/52c69892db98/materials-10-00848-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a053/5578214/3feefa46775d/materials-10-00848-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a053/5578214/a67b8bb5f326/materials-10-00848-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a053/5578214/7c9d705a6928/materials-10-00848-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a053/5578214/d68d2eef0774/materials-10-00848-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a053/5578214/54660e4c6284/materials-10-00848-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a053/5578214/68f3f3151c8a/materials-10-00848-g012.jpg

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