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轻质和固定式电池堆中薄膜电解质金属支撑固体氧化物燃料电池的运行:材料与微观结构方面

Operation of Thin-Film Electrolyte Metal-Supported Solid Oxide Fuel Cells in Lightweight and Stationary Stacks: Material and Microstructural Aspects.

作者信息

Roehrens Daniel, Packbier Ute, Fang Qingping, Blum Ludger, Sebold Doris, Bram Martin, Menzler Norbert

机构信息

Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research, IEK-1: Materials Synthesis and Processing, Jülich 52425, Germany.

Christian Doppler Laboratory for Interfaces in Metal-Supported Electrochemical Energy Converters, Jülich 52425, Germany.

出版信息

Materials (Basel). 2016 Sep 8;9(9):762. doi: 10.3390/ma9090762.

Abstract

In this study we report on the development and operational data of a metal-supported solid oxide fuel cell with a thin film electrolyte under varying conditions. The metal-ceramic structure was developed for a mobile auxiliary power unit and offers power densities of 1 W/cm² at 800 °C, as well as robustness under mechanical, thermal and chemical stresses. A dense and thin yttria-doped zirconia layer was applied to a nanoporous nickel/zirconia anode using a scalable adapted gas-flow sputter process, which allowed the homogeneous coating of areas up to 100 cm². The cell performance is presented for single cells and for stack operation, both in lightweight and stationary stack designs. The results from short-term operation indicate that this cell technology may be a very suitable alternative for mobile applications.

摘要

在本研究中,我们报告了一种带有薄膜电解质的金属支撑固体氧化物燃料电池在不同条件下的开发情况和运行数据。这种金属陶瓷结构是为移动辅助动力单元开发的,在800℃时功率密度可达1W/cm²,并且在机械、热和化学应力下具有鲁棒性。使用可扩展的适配气流溅射工艺,在纳米多孔镍/氧化锆阳极上涂覆了一层致密的薄钇掺杂氧化锆层,该工艺可对面积达100cm²的区域进行均匀涂覆。给出了单电池以及轻型和固定式电池堆设计的电池堆运行的性能。短期运行结果表明,这种电池技术可能是移动应用的一种非常合适的替代方案。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/641f/5457052/0534849788a0/materials-09-00762-g001.jpg

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