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碳的百年简史

A brief 100 year history of carbon.

作者信息

Kemp Terence J

出版信息

Sci Prog. 2017 Sep 1;100(3):293-298. doi: 10.3184/003685017X14994318577435. Epub 2017 Aug 5.

DOI:10.3184/003685017X14994318577435
PMID:28779761
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10365194/
Abstract

Elemental carbon has been known from time immemorial in its forms of diamond and graphite, while the Industrial Revolution was powered by coal. The molecular structures of diamond and graphite were established following the inception of X-ray crystallography while the complex natures of charcoal and coal have been investigated for 100 years. Recent developments in activated charcoal are described in an article in this issue of Science Progress. However, no-one could have guessed that carbon would have presented such structural surprises as those of C60 fullerene, carbon nanotubes, and graphene. Materials science has benefited from the discovery of carbon fibres, and our understanding of the spectroscopy and bonding in the simplest carbon molecule, C2, has reached new depths.

摘要

自古以来,人们就知道碳元素以钻石和石墨的形式存在,而工业革命则由煤炭驱动。随着X射线晶体学的出现,钻石和石墨的分子结构得以确定,而木炭和煤炭的复杂性质也已经研究了100年。本期《科学进展》的一篇文章描述了活性炭的最新进展。然而,没有人能猜到碳会呈现出诸如C60富勒烯、碳纳米管和石墨烯这样的结构惊喜。材料科学受益于碳纤维的发现,我们对最简单的碳分子C2的光谱学和键合的理解也达到了新的深度。

相似文献

1
A brief 100 year history of carbon.碳的百年简史
Sci Prog. 2017 Sep 1;100(3):293-298. doi: 10.3184/003685017X14994318577435. Epub 2017 Aug 5.
2
Unfolding the fullerene: nanotubes, graphene and poly-elemental varieties by simulations.通过模拟展开富勒烯:纳米管、石墨烯和多元素变体。
Adv Mater. 2012 Sep 18;24(36):4956-76. doi: 10.1002/adma.201202322. Epub 2012 Aug 14.
3
Structural, electronic, optical and vibrational properties of nanoscale carbons and nanowires: a colloquial review.纳米碳和纳米线的结构、电子、光学和振动特性:通俗评论。
J Phys Condens Matter. 2010 Aug 25;22(33):334201. doi: 10.1088/0953-8984/22/33/334201. Epub 2010 Aug 4.
4
Development of a ReaxFF potential for carbon condensed phases and its application to the thermal fragmentation of a large fullerene.用于碳凝聚相的ReaxFF势函数的开发及其在大型富勒烯热裂解中的应用。
J Phys Chem A. 2015 Jan 29;119(4):571-80. doi: 10.1021/jp510274e. Epub 2015 Jan 21.
5
FTIR Spectroscopy for Carbon Family Study.傅里叶变换红外光谱法在碳家族研究中的应用。
Crit Rev Anal Chem. 2016 Nov;46(6):502-20. doi: 10.1080/10408347.2016.1157013. Epub 2016 Mar 3.
6
Fullerene-based anodic stripping voltammetry for simultaneous determination of Hg(II), Cu(II), Pb(II) and Cd(II) in foodstuff.基于富勒烯的阳极溶出伏安法同时测定食品中 Hg(II)、Cu(II)、Pb(II)和 Cd(II)
Mikrochim Acta. 2018 May 1;185(5):274. doi: 10.1007/s00604-018-2803-9.
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The carbon nanocosmos: novel materials for the twenty-first century.碳纳米世界:21世纪的新型材料。
Philos Trans A Math Phys Eng Sci. 2003 Dec 15;361(1813):2789-806. doi: 10.1098/rsta.2003.1262.
8
Modular Covalent Graphene Functionalization with C and the Endohedral Fullerene Sc N@C : A Facile Entry to Synthetic-Carbon-Allotrope Hybrids.用C和内嵌富勒烯Sc N@C进行模块化共价石墨烯功能化:通往合成碳同素异形体杂化物的便捷途径。
Angew Chem Int Ed Engl. 2019 Jan 14;58(3):816-820. doi: 10.1002/anie.201811864. Epub 2018 Dec 17.
9
Advances in preparation, mechanism and applications of various carbon materials in environmental applications: A review.各种碳材料在环境应用中的制备、机制和应用进展:综述。
Chemosphere. 2022 Aug;300:134596. doi: 10.1016/j.chemosphere.2022.134596. Epub 2022 Apr 15.
10
The sphere-in-contact model of carbon materials.碳材料的球接触模型。
J Mol Model. 2016 Jan;22(1):40. doi: 10.1007/s00894-015-2895-7. Epub 2016 Jan 20.

本文引用的文献

1
Comparative study of different activation treatments for the preparation of activated carbon: a mini-review.用于制备活性炭的不同活化处理的比较研究:一篇综述。
Sci Prog. 2017 Sep 1;100(3):299-312. doi: 10.3184/003685017X14967570531606. Epub 2017 Aug 5.
2
The 2015 Paris Climate Change Conference: COP21.2015年巴黎气候变化大会:第21届联合国气候变化框架公约缔约方大会
Sci Prog. 2016;99(Pt 1):97-104. doi: 10.3184/003685016X14528569315192.
3
Puzzles in bonding and spectroscopy: the case of dicarbon.键合与光谱学中的谜题:以双碳为例。
Sci Prog. 2016;99(Pt 1):1-58. doi: 10.3184/003685016X14509452393033.
4
Laboratory confirmation of C60(+) as the carrier of two diffuse interstellar bands.实验室确认 C60(+) 为两个弥漫星际带的载体。
Nature. 2015 Jul 16;523(7560):322-3. doi: 10.1038/nature14566.
5
Astrochemistry: Fullerene solves an interstellar puzzle.
Nature. 2015 Jul 16;523(7560):296-7. doi: 10.1038/523296a.
6
Synthesis and selected properties of graphene and graphene mimics.石墨烯及其类似物的合成及特性研究。
Acc Chem Res. 2013 Jan 15;46(1):149-59. doi: 10.1021/ar300033m. Epub 2012 Jun 27.
7
Advancing risk assessment of engineered nanomaterials: application of computational approaches.推进工程纳米材料风险评估:计算方法的应用。
Adv Drug Deliv Rev. 2012 Dec;64(15):1663-93. doi: 10.1016/j.addr.2012.05.014. Epub 2012 Jun 1.
8
Medicinal applications of fullerenes.富勒烯的医学应用。
Int J Nanomedicine. 2007;2(4):639-49.