氧化还原促进的金属有机材料的缔合组装
Redox-promoted associative assembly of metal-organic materials.
作者信息
Glavinović Martin, Qi Feng, Katsenis Athanassios D, Friščić Tomislav, Lumb Jean-Philip
机构信息
Department of Chemistry , McGill University , 801 Sherbrooke St. West Montreal , Quebec H3A 0B8 , Canada . Email:
出版信息
Chem Sci. 2016 Jan 1;7(1):707-712. doi: 10.1039/c5sc02214b. Epub 2015 Oct 9.
We develop an associative synthesis of metal-organic materials that combines solid-state metal oxidation and coordination-driven self-assembly into a one-step, waste-free transformation. The methodology hinges on the unique reactivity of -quinones, which we introduce as versatile oxidants for mechanochemical synthesis. Our strategy opens a previously unexplored route to paramagnetic metal-organic materials from elementary metals.
我们开发了一种金属有机材料的关联合成方法，该方法将固态金属氧化和配位驱动的自组装结合为一步无废转化过程。该方法依赖于对苯二醌的独特反应性，我们将其作为机械化学合成的通用氧化剂引入。我们的策略为从单质金属制备顺磁性金属有机材料开辟了一条前所未有的途径。
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