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锂离子电池负极老化机制

Lithium Ion Battery Anode Aging Mechanisms.

作者信息

Agubra Victor, Fergus Jeffrey

机构信息

Materials Research and Education Center, Auburn University, 275 Wilmore Laboratories Auburn, AL 36849, USA.

出版信息

Materials (Basel). 2013 Mar 27;6(4):1310-1325. doi: 10.3390/ma6041310.

DOI:10.3390/ma6041310
PMID:28809211
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5452304/
Abstract

Degradation mechanisms such as lithium plating, growth of the passivated surface film layer on the electrodes and loss of both recyclable lithium ions and electrode material adversely affect the longevity of the lithium ion battery. The anode electrode is very vulnerable to these degradation mechanisms. In this paper, the most common aging mechanisms occurring at the anode during the operation of the lithium battery, as well as some approaches for minimizing the degradation are reviewed.

摘要

诸如锂金属沉积、电极上钝化表面膜层的生长以及可循环锂离子和电极材料的损失等降解机制会对锂离子电池的寿命产生不利影响。阳极电极极易受到这些降解机制的影响。本文综述了锂电池运行过程中阳极发生的最常见老化机制,以及一些将降解降至最低的方法。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f00/5452304/40ba2c0a0caf/materials-06-01310-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f00/5452304/29a240a53d61/materials-06-01310-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f00/5452304/bf100ef79c26/materials-06-01310-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f00/5452304/a37f61e1b6d0/materials-06-01310-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f00/5452304/7a2585d4c696/materials-06-01310-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f00/5452304/5acd3800534a/materials-06-01310-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f00/5452304/e09d49959aeb/materials-06-01310-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f00/5452304/40ba2c0a0caf/materials-06-01310-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f00/5452304/29a240a53d61/materials-06-01310-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f00/5452304/bf100ef79c26/materials-06-01310-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f00/5452304/a37f61e1b6d0/materials-06-01310-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f00/5452304/7a2585d4c696/materials-06-01310-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f00/5452304/5acd3800534a/materials-06-01310-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f00/5452304/e09d49959aeb/materials-06-01310-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f00/5452304/40ba2c0a0caf/materials-06-01310-g007.jpg

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本文引用的文献

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Rev Sci Instrum. 2011 Jul;82(7):075107. doi: 10.1063/1.3607961.
2
In situ NMR observation of the formation of metallic lithium microstructures in lithium batteries.在电池中通过原位 NMR 观察金属锂微结构的形成。
Nat Mater. 2010 Jun;9(6):504-10. doi: 10.1038/nmat2764. Epub 2010 May 16.
采用零和脉冲法对不同荷电状态(SOC)的磷酸铁锂(LiFePO)电池老化机制的研究。
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Overlooked Promising Green Features of Electrospun Cellulose-Based Fibers in Lithium-Ion Batteries.锂离子电池中电纺纤维素基纤维被忽视的潜在绿色特性
ACS Omega. 2023 Nov 7;8(46):43388-43407. doi: 10.1021/acsomega.3c05068. eCollection 2023 Nov 21.
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Strategies for Controlling or Releasing the Influence Due to the Volume Expansion of Silicon inside Si-C Composite Anode for High-Performance Lithium-Ion Batteries.用于高性能锂离子电池的硅碳复合负极中控制或释放硅体积膨胀影响的策略
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