Masek Anna, Kosmalska Anna
Faculty of Chemistry, Institute of Polymer and Dye Technology, Lodz University of Technology, Łódź, Poland.
Front Bioeng Biotechnol. 2022 Aug 17;10:912052. doi: 10.3389/fbioe.2022.912052. eCollection 2022.
Among the many possible types of polymer composite materials, the most important are nanocomposites and biocomposites, which have received tremendous attention in recent years due to their unique properties. The fundamental benefits of using biocomposites as alternative materials to "petroleum-based" products are certainly shaping current development trends and setting directions for future research and applications of polymer composites. A dynamic growth of the production and sale of biocomposites is observed in the global market, which results not only from the growing interest and demand for this type of materials, but also due to the fact that for the developed and modified, thus improved materials, the area of their application is constantly expanding. Already today, polymer composites with plant raw materials are used in various sectors of the economy. In particular, this concerns the automotive and construction industries, as well as widely understood packaging. Bacterial cellulose, for example, also known as bionanocellulose, as a natural polymer with specific and unique properties, has been used extensively,primarily in numerous medical applications. Intensive research is also being carried out into composites with natural fibres composed mainly of organic compounds such as cellulose, hemicellulose and lignin. However, three aspects seem to be associated with the popularisation of biopolymers: performance, processing and cost. This article provides a brief overview of the topic under discussion. What can be the technological limitations considering the methods of obtaining polymer composites with the use of plant filler and the influence on their properties? What properties of cellulose constitute an important issue from the point of view of its applicability in polymers, in the context of compatibility with the polymer matrix and processability? What can be the ways of changing these properties through modifications, which may be crucial from the point of view of the development directions of biopolymers and bioplastics, whose further new applications will be related, among others, to the enhancement of properties? There still seems to be considerable potential to improve the cellulose material composites being produced, as well as to improve the efficiency of their manufacturing. Nevertheless, the material still needs to be well optimized before it can replace conventional materials at the industrial level in the near future. Typically, various studies discuss their comparison in terms of production, properties and highly demanding applications of plant or bacterial nanocellulose. Usually, aspects of each are described separately in the literature. In the present review, several important data are gathered in one place, providing a basis for comparing the types of cellulose described. On the one hand, this comparison aims to demonstrate the advantage of bacterial cellulose over plant cellulose, due to environmental protection and its unique properties. On the other hand, it aims to prepare a more comprehensive point of view that can objectively help in deciding which cellulosic raw material may be more suitable for a particular purpose, bacterial cellulose or plant cellulose.
在众多可能的聚合物复合材料类型中,最重要的是纳米复合材料和生物复合材料,由于其独特的性能,近年来它们受到了极大的关注。使用生物复合材料替代“石油基”产品的根本好处无疑正在塑造当前的发展趋势,并为聚合物复合材料的未来研究和应用指明方向。全球市场上生物复合材料的生产和销售呈现出动态增长,这不仅是因为对这类材料的兴趣和需求不断增加,还因为对于经过开发和改性从而性能得到改善的材料,其应用领域在不断扩大。如今,含有植物原料的聚合物复合材料已被应用于经济的各个领域。特别是在汽车和建筑行业,以及广义的包装领域。例如,细菌纤维素,也被称为生物纳米纤维素,作为一种具有特定和独特性能的天然聚合物,已被广泛应用,主要用于众多医疗应用中。针对主要由纤维素、半纤维素和木质素等有机化合物组成的天然纤维复合材料也正在进行深入研究。然而,生物聚合物的推广似乎与三个方面相关:性能、加工和成本。本文对所讨论的主题进行了简要概述。考虑到使用植物填料获得聚合物复合材料的方法及其对材料性能的影响,可能存在哪些技术限制?从纤维素在聚合物中的适用性、与聚合物基体的相容性和可加工性的角度来看,纤维素的哪些性能构成了一个重要问题?通过改性改变这些性能的方法有哪些,从生物聚合物和生物塑料的发展方向来看,这些方法可能至关重要,其进一步的新应用将尤其与性能提升相关?目前生产的纤维素材料复合材料以及其制造效率似乎仍有相当大的提升潜力。然而,在不久将来能够在工业层面替代传统材料之前,该材料仍需进行充分优化。通常,各种研究讨论了植物或细菌纳米纤维素在生产、性能和高要求应用方面的比较。通常,文献中会分别描述每个方面。在本综述中,将几个重要数据集中在一处,为比较所描述的纤维素类型提供了依据。一方面,这种比较旨在展示细菌纤维素相对于植物纤维素的优势,这得益于其环保特性及其独特性能。另一方面,旨在形成一个更全面的观点,以便客观地帮助确定哪种纤维素原料可能更适合特定用途,是细菌纤维素还是植物纤维素。